Chemistry of hydrocarbon compounds – Adding hydrogen to unsaturated bond of hydrocarbon – i.e.,... – With subsequent diverse conversion
Patent
1996-10-15
1998-06-23
Caldarola, Glenn
Chemistry of hydrocarbon compounds
Adding hydrogen to unsaturated bond of hydrocarbon, i.e.,...
With subsequent diverse conversion
585266, 585304, 585317, 585734, 4236583, C07C 522, C07C 100, C07C 513
Patent
active
057707812
ABSTRACT:
A method for reducing the benzene content and isomerizing at least a portion of a C.sub.5 /C.sub.6 paraffinic stream using a hydrogen stream containing more than 0.1 ppmv of carbon monoxide, carbon dioxide or a mixture thereof, the method comprising: charging a C.sub.5 /C.sub.6 paraffin stream containing benzene to a benzene saturation zone; charging a hydrogen stream containing at least 0.1 ppmv of at least one carbon oxide to the benzene saturation zone; saturating at least a major portion of the benzene and methanating at least a major portion of the carbon oxide present in the benzene saturation zone to produce a reduced benzene content C.sub.5 and C.sub.6 paraffinic stream and a reduced carbon oxide content hydrogen stream; recovering the reduced benzene content C.sub.5 and C.sub.6 paraffinic stream and the reduced carbon oxide content hydrogen stream; drying at least a portion of the reduced carbon oxide content hydrogen stream to produce a dried reduced carbon oxide content hydrogen stream; charging at least a portion of the dried reduced carbon oxide content hydrogen stream to a C.sub.5 /C.sub.6 isomerization zone; charging at least a portion of the reduced benzene content C.sub.5 /C.sub.6 paraffinic stream to the C.sub.5 /C.sub.6 isomerization zone; and, isomerizing at least a portion of the reduced benzene content C.sub.5 /C.sub.6 paraffinic stream in the C.sub.5 /C.sub.6 isomerization zone to produce an isomerized C.sub.5 /C.sub.6 paraffin stream.
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Pedersen Michael J.
Voss Andrew P.
Atlantic Richfield Company
Bullock In Suk
Caldarola Glenn
Scott F. Lindsey
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