Method for electrochemical etching of semiconductor material...

Semiconductor device manufacturing: process – Chemical etching – Liquid phase etching

Reexamination Certificate

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C438S042000, C438S093000, C205S655000, C205S656000, C204S242000

Reexamination Certificate

active

07494936

ABSTRACT:
A method for electrochemical etching of a semiconductor material using positive potential dissolution (PPD) in solutions that do not contain hydrofluoric acid (HF-free solutions). The method includes immersing an as-cut semiconductor material in an etching solution, and positive biasing at atypically highly positive (anodic) potentials, thereby significantly increasing the value of the anodic current density (measured as A/cm2) of the semiconductor material. The application of positive biasing at atypically highly positive (anodic) potentials, is combined with specifically controlling and directing illumination on the semiconductor material surface contacted and wetted by the etching solution. This is done for a necessary and sufficient period of time to enable a positive synergistic effect on the rate and extent of etching of the semiconductor material therefrom.

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patent: 6521118 (2003-02-01), Starosvetsky et al.
patent: 2005/0148198 (2005-07-01), Ein-Eli et al.
patent: 40 36 895 (1992-05-01), None
R. A. Wind et al., Orientation-resolved chemical kinetics: using microfabrication to unravel the complicated chemistry of KOH/Si etching, J. Phys. Chern B.106(7), 1557-1569 (2002).
I. Zubel and M. Kramkowska, The effect of isopropyl alcohol on etching rate and roughness of (1 0 0) Si surface etched in KOH and TMAH solutions, Sensors and Actuators A. Physical, A93(2). 138-147 (2001).

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