Bleaching and dyeing; fluid treatment and chemical modification – Dye or potential dye composition – additive – treatment,...
Reexamination Certificate
2000-12-13
2003-09-02
Einsmann, Margaret (Department: 1751)
Bleaching and dyeing; fluid treatment and chemical modification
Dye or potential dye composition, additive, treatment,...
C008S926000
Reexamination Certificate
active
06613103
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
This invention relates to a process for dyeing fabrics comprising elastomeric fiber and, more particularly, to such a process which results in dyed fabrics which are substantially free of a particular kind of undesirable nonuniformity, “fractures”.
2. Discussion of Background Art
A variety of dyeing and wet-finishing processes have been applied to fabrics. Martin White,
Rev. Prog. Coloration,
Vol. 28, 1998, pp. 80-94, discloses jet-dyeing of spandex-containing fabrics. N. E. Houser,
AATCC Symposium on Elastic Fabrics,
Nov. 2-3, 1998; pp. 192-201, discloses heat setting spandex-containing fabrics after relaxation and before dyeing as an aid in avoiding crease, rope, and crack marks. U.S. Pat. No. 5,399,616, British Patent 1,583,795, and L. Barringer, Jr.,
American Dyestuff Reporter,
September 1994, pp. 68ff, disclose the use of lubricants in textile wet processing.
The steps in conventional jet-dye processes for fabric comprising elastomeric fibers have been slitting (when the fabric is a circular knit), pre-heat-setting, tacking the fabric into a tubular form, dyeing (adding the fabric to a dyebath, then adding lubricant and dye, heating the bath at 0.5-1.0° C./minute to the dyeing temperature, cooling the bath at 0.5° C./minute), de-tacking the fabric, drying it, and heat-setting the fabric.
Fractures in elastomeric fiber-containing circular knit fabrics have not been eliminated without slitting, heat setting, and tacking the fabrics before dyeing, and a simpler method of eliminating fractures is still needed.
SUMMARY OF THE INVENTION
The process of this invention for jet-dyeing a fabric comprising an elastomeric fiber comprise the steps of:
(a) providing a jet-dyeing machine;
(b) adding water and a textile dyebath lubricant to the machine to form a bath, and heating the bath to at least about 40° C.;
(c) adding the fabric to the bath after step b);
(d) adding at least one dye to the bath; and
(e) heating the bath to the dyeing temperature.
DETAILED DESCRIPTION OF THE INVENTION
By “elastomeric fiber” is meant a staple fiber or continuous filament which, free of diluents, has a break elongation in excess of 100% independent of any crimp and which when stretched to twice its length, held for one minute, and then released, retracts to less than 1.5 times its original length within one minute of being released. Such fibers include spandex, polyetherester fiber, and elastoester, and can be covered with other, non-elastomeric fibers or can be bare (uncovered). “Spandex” is a manufactured fiber in which the fiber-forming substance is a long chain synthetic polymer comprised of at least 85% by weight of a segmented polyurethane.
By “fracture” is meant a short (typically 3 cm or less), sharply defined mark that can appear in a fabric during jet-dyeing, possibly resulting from one or two elastomeric fibers becoming displaced from the plane of the fabric. Fractures are unique to fabrics comprising elastomeric fibers and are so named because, to the naked eye, they can look like cuts in the fabric. Fractures are aligned in the direction of the elastomeric fiber. For example, fractures can appear in the cross-direction in circular knits and either in the cross-direction or the machine-direction in warp knits and wovens, depending on the elastomeric fiber orientation. When the elastomeric fiber is present in the fabric in two directions as in bi-stretch fabrics, fractures can appear as crosses, x's, crow's feet, and the like. In contrast, “creases” are typically longer than fractures, less sharply defined, and are oriented, sometimes obliquely, in the dyeing-machine-direction regardless of fabric machine direction. “Crack marks”, which are like sharp creases, always appear in the general direction of the long dimension of the fabric, regardless of elastomeric fiber direction, can be longer and are less sharply defined than fractures. It is speculated that creases and crack marks result from folding of the fabric during wet processing, while fractures result either from a) highly localized drawing and permanent setting of one or two elastomeric fibers at a time after which the resulting longer fiber(s) must bulge out of the plane of the fabric for a short distance, or b) a highly localized inability to accommodate elastomeric fiber retractive forces generated elsewhere in the fabric during wet-finishing. “Rope marks” are dye-deficient areas in a fabric resulting from the inability of dye to penetrate the fabric in the vicinity of rope used to constrain the fabric during dyeing. “Not substantially heat-set” means that a fabric containing a spandex comprising polyurethaneurea has not been heated above about 320° F. (160° C.) under dry conditions or above about 250° F. (121° C.) with steam. For a fabric containing a polyetherester fiber or a spandex comprising polyurethane, it means the fabric has not been heated above about 280° F. (138° C.) under dry conditions or above about 220° F. (105° C.) with steam.
It has now been unexpectedly found that by carrying out the dyeing of a fabric containing elastomeric fiber in a particular way, fractures can be avoided without the necessity of heat-setting the fabric before dyeing it. Further, the present process also gives much higher dye yields, an additional unexpected and beneficial result.
In the process of the invention, an aqueous bath is prepared in a jet-dyeing machine by adding water and a textile dyebath lubricant. The bath is pre-heated to at least about 40° C., typically about 40-60° C. While creases and crack marks can be reduced or eliminated by adding lubricant to the bath after adding the fabric, doing so does not have the same beneficial effect on fractures, and it is a requirement of the inventive process that the water and lubricant be added to the dyeing machine before the fabric is added to the resulting bath. It is, however, immaterial whether the lubricant is added before or after the water is added, or before or after the bath is pre-heated. The lubricant can be used at a level of about 1.0-5.0 g/l, based on the water volume in the bath. The fabric and at least one dye are then added to the bath. After each of the steps of adding the lubricant and adding the fabric, it can be helpful to run the dyeing machine for 5-10 minutes, thoroughly to mix the water and lubricant and to wet the fabric, respectively. However, to minimize further the formation of fractures, it is preferred that the fabric spend less than about 45 minutes in the bath (during fabric wetting and dye addition) before beginning to heat the bath to the dyeing temperature, which heating can take place over a period of less than about 100 minutes. After dyeing is complete, the bath can be cooled. It is preferred that the dyebath be heated rapidly, for example at an average rate of at least about 1° C./minute, and cooled rapidly, for example also at an average rate of at least about 1° C./minute, for maximum avoidance of fractures.
Both tank-type and horizontal (low profile) machines can be used, as can any desired liquor ratio (for example 7:1 to 25:1 weight ratio of dyebath to fabric). Optional pre-process preparations can include relaxing the fabric to avoid structural distortion and uneven dyeing, for example by steaming or pre-scouring. Optional post-dyeing operations can include reduction clearing, soaping, wet or dry heat setting, and the like.
The process of the invention can be carried out with a Samil horizontal (low profile) jet dyeing machine with single jersey circular knits (e.g., 10 wt % Lycra® spandex) and rib knits (e.g., 4 wt % Lycra® spandex) in which the companion fiber can be polyester, nylon, acetate, or rayon, utilizing a lubricant such as 1.5 g/l Lubrigen® BA, resulting in fracture-free fabrics. Due to the elimination of pre-heat-setting, the total dye cycle time can be reduced from 6 hours to 4 hours. Also, dye uptake can be more level than in conventional processes.
In addition to the elastomeric fiber (which is preferably spandex), fibers that can be used in the fabric to
Immediato Robert F
Luongo Ronald R
E. I. du Pont de Nemours and Company
Einsmann Margaret
Elhilo Eisa
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