Method for dissolving plutonium oxide with HI and separating plu

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Radioactive metal

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2523011R, 423 20, 423251, C01G 5600

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active

041349601

ABSTRACT:
PuO.sub.2 -containing solids, particularly residues from incomplete HNO.sub.3 dissolution of irradiated nuclear fuels, are dissolved in aqueous HI. The resulting solution is evaporated to dryness and the solids are dissolved in HNO.sub.3 for further chemical reprocessing. Alternatively, the HI solution containing dissolved Pu values, can be contacted with a cation exchange resin causing the Pu values to load the resin. The Pu values are selectively eluted from the resin with more concentrated HI.

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patent: 4025602 (1977-05-01), Campbell et al.
patent: 4069293 (1978-01-01), Tallent
Holley et al., "Proc. Second U.N. Intl. Conf. Peaceful Uses of Atomic Energy", vol. 6, p. 216, United Nations, Geneva (1958).
Cleveland I, "The Chemistry of Plutonium", pp. 142-148, 301-302, 574-575, Gordon and Breach Science Publishers, (1970), New York.
Cleveland II, "J. Inorg. Nucl. Chem.", 26, 1470-1471, (1964).

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