Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Halogenous component
Patent
1980-04-24
1981-09-29
Peters, G. O.
Chemistry of inorganic compounds
Modifying or removing component of normally gaseous mixture
Halogenous component
423464, 423500, 264117, B01D 5334
Patent
active
042922879
ABSTRACT:
This invention is a process for the direct recovery of gaseous fluorine from waste-gas streams or the like. The process comprises passing the gas stream through a bed of anhydrous K.sub.3 NiF.sub.6 pellets to fluorinate the same to K.sub.3 NiF.sub.7 and subsequently desorbing the fluorine by heating the K.sub.3 NiF.sub.7 pellets to a temperature re-converting them to K.sub.3 NiF.sub.6. The efficiency of the fluorine-absorption step is maximized by operating in a selected and conveniently low temperature. The desorbed fluorine is highly pure and is at a pressure of several atmospheres. Preferably, the K.sub.3 NiF.sub.6 pellets are prepared by a method including the steps of forming agglomerates of hydrated K.sub.3 NiF.sub.5, sintering the agglomerates to form K.sub.3 NiF.sub.5 pellets of enhanced reactivity with respect to fluorine, and fluorinating the sintered pellets to K.sub.3 NiF.sub.6.
REFERENCES:
patent: 3372004 (1968-03-01), Richardson et al.
patent: 3989808 (1976-11-01), Asprey
Orlett Michael J.
Saraceno Anthony J.
Besha Richard G.
Hamel Stephen D.
Lewis Fred O.
Peters G. O.
The United States of America as represented by the United States
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