Method for direct use of chromite ore in the production of stain

Specialized metallurgical processes – compositions for use therei – Processes – Producing or treating free metal

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75503, 75540, 75623, 75708, 420116, C21B 1500, C21C 700, C22B 404, C22B 900

Patent

active

057025029

ABSTRACT:
A three-stage process for obtaining metallic Cr units insitu during the production of stainless steel. Raw chromite ore or a concentrate produced from chromite ore is mixed with a carbonaceous reductant and slagging agents are added to an iron bath (24) for smelting and refining in a refining reactor (10). During the first stage, partially metallized chromite is smelted by carbon in the reactor that is top-and bottom-blown with oxygen and oxygen-containing gases respectively to produce a chromium alloy bath having a carbon content well below saturation. In the second stage, the alloy bath is decarburized by being bottom stirred with the oxygen-containing gas to the final bath carbon specification. In the third stage, the alloy bath is reduced by a metalloid reductant such as silicon or aluminum and again bottom stirred but with a non-oxidizing gas to achieve a high chromium yield. The reactor includes a top lance (18) extending through a throat (14) with a lower portion (20) of the lance extending to a point just above the bath and means (22) such as a tuyere or porous plug mounted at or near a bottom (16) and extending through a refractory lining (12) for stirring the iron bath containing dissolved carbon. Lance (18) includes a central passage (34) for injecting a compact, focused jet oxygen gas (30) that can penetrate through a slag layer (26) for decarburization of the iron bath and an outer passage (32) for discharging an oxygen gas (28) above the bath for post-combustion of CO to CO.sub.2. Passage (32) includes a plurality of evenly spaced annular diverging nozzles (33). The lance also includes a pair of concentric conduits (36) and (38) for conducting a coolant.

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Masterson, I.F., "Argon Oxygen Decarburization (AOD)", ASM Handbook, v15. pp. 426-429, Sep. 1988.
Burgmann, W., "Vacuum Oxygen Decarburization (VODC)", ASM Handbook, v15. pp. 429-431, Sep. 1988.
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