Method for detecting trace impurities in gases

Radiant energy – Methods including separation or nonradiant treatment of test...

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G01N 3100, G01N 3300

Patent

active

042648149

ABSTRACT:
A technique for considerably improving the sensitivity and specificity of infrared spectrometry as applied to quantitative determination of trace impurities in various carrier or solvent gases is presented. A gas to be examined for impurities is liquefied and infrared absorption spectra of the liquid are obtained. Spectral simplification and number densities of impurities in the optical path are substantially higher than are obtainable in similar gas-phase analyses. Carbon dioxide impurity (.about.2 ppm) present in commercial Xe and ppm levels of Freon 12 and vinyl chloride added to liquefied air are used to illustrate the method.

REFERENCES:
patent: 2917629 (1959-12-01), Andrychuk
patent: 3530292 (1970-09-01), Hill

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