Method for desulfurizing thiophene derivatives contained in...

Mineral oils: processes and products – Refining – Sulfur removal

Reexamination Certificate

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C208S196000, C208S20800M, C208S226000, C208S240000

Reexamination Certificate

active

10169030

ABSTRACT:
The invention concerns a method for selectively desulphurizing thiopene compounds contained in hydrocarbons derived from crude oil distillation, whether refined or not, which consists in oxidising the thiophene sulphur atoms into sulphone in the presence of an oxidising agent and in separating said sulphonated compounds from said hydrocarbons. The invention is characterised in that it consists in oxidising the thiophene compounds in a two-phase turbulent medium comprising a hydrocarbon phase and an aqueous phase, in the presence of at least an oxidising agent soluble in at least one of the two phases and of at least a metal catalyst in soluble or dispersed form in a liquid of in solid form, separation and oxidation occurring simultaneously.

REFERENCES:
patent: 3039855 (1962-06-01), Urban
patent: 3445380 (1969-05-01), Urban
patent: 3551328 (1970-12-01), Cole et al.
patent: 3647683 (1972-03-01), Kelly
patent: 3816301 (1974-06-01), Sorgenti
patent: 6171478 (2001-01-01), Cabrera et al.
patent: 6368495 (2002-04-01), Kocal et al.
patent: 29472 (1981-06-01), None
patent: 115382 (1984-08-01), None
patent: 565324 (1993-10-01), None
patent: 1595726 (1970-06-01), None
SU1203102A abstract 01-1985.
SU1549985A abstract 03-1990.

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