Method for decomposing N20 utilizing catalysts comprising calcin

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Nitrogen or nitrogenous component

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502 80, B01J 800

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active

054076528

ABSTRACT:
The invention describes a highly efficient catalytic pollution control process for removing N.sub.2 O from gaseous mixtures. The process utilizes catalysts derived from anionic clay minerals, which after appropriate heat activation, provide superior N.sub.2 O decomposition activity. The catalytic process comprises contacting an N.sub.2 O -containing gaseous mixture with the decomposition catalyst under conditions sufficient to convert the N.sub.2 O into gaseous nitrogen and gaseous oxygen. The process catalysts are derived from anionic clay materials such as the hydrotalcites, sjogrenites and pyroaurites.

REFERENCES:
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"Structure and Catalytic Activity of Iron Oxide and Magnesium Oxide Solid Solutions" Schiavello et al.; (J. Chem. Soc. Faraday Trans.); 1, 71(8); (no date).
"Structure and Catalytic Activity of Co.sub.x Mg.sub.1-x Al.sub.2 O.sub.4 Spinel Solutions"; Angeletti et al.; (J. Chem. Soc. Faraday Trans.); 1, 74(7); (no date).
"Catalytic Reactions by Thermally Activated, Synthetic, Anionic Clay Materials" Reichle; (Journal of Catalysis) 94; 1985 pp. 547-557 (odd pages only).
Thiemens and Trogler, Science, 251 (1991) 932.
M. Schiavello and coworkers, (J. Chem. Soc. Faraday Trans. 1, 71(8), 1642-8).
P. Porta and coworkers (J. Chem. Soc. Faraday Trans. 1, 74(7), 1595-603).
W. Reichle (Journal of Catalysis 94 (1985) 547) (odd pages).

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