Method for crosslinking reactive polyolefins via a rhodium catal

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525106, 525478, 528 15, 528 31, 556479, 556487, C08F 800

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048310816

ABSTRACT:
The present invention is directed to a method for crosslinking reactive polyolefins using a rhodium catalyzed hydrosilation reaction and novel siloxanes as crosslinkers.
Also disclosed are novel siloxane compounds which are useful in the crosslinking of polyolefins and polyolefin compositions which have been crosslinked through use of the claimed process and siloxane crosslinkers.

REFERENCES:
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patent: 4414376 (1983-11-01), Siedle
patent: 4579964 (1986-04-01), Totten et al.
patent: 4587137 (1986-05-01), Eckberg
G. Cameron et al., Polymerization of Poly(Dimethylsiloxane)Macromers, Polymer, vol. 26, pp. 437-442, 1985.
M. Llorente et al., Model Networks of End-Linked Poly(Dimethylsiloxane)Chains, Macromolecules, vol. 13, pp. 681-685, 1985.
Lukevics et al., Hydrosilation: Recent Achievements, Journal of Organometallic Chemistry, No. 5, pp. 1-179, 1977.

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