Method for converting organic chloroformate to the corresponding

Details Method for converting organic chloroformate to the corresponding Method for converting organic chloroformate to the corresponding

1986-09-15

1987-12-22

Mars, Howard T.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568606, 568608, 568610, 568655, 568669, 568681, 570101, 570186, 570181, 570201, C07C 4101, C07C 1902, C07C 1700

Patent

active

047147857

ABSTRACT:
Organic haloformate, e.g., chloroformate, compounds are converted to their corresponding halides, e.g., chlorides, by heating the haloformate, e.g., between 90.degree. C. and 150.degree. C., in the presence of a catalytic amount of a carbon catalyst for a time sufficient to convert the haloformate to the corresponding halide.

REFERENCES:
patent: 4622431 (1986-11-01), Briody et al.
Rearrangement Occurring During Thermal Decomposition of Alkyl Chloroformates, P. W. Clinch, et al., J. Chem. Soc. B, pp. 747-751 (1971)(4).
The Chemistry of Chloroformates, M. Matzner et al., Chem. Rev. 64, pp. 645-661 and 677-687 (1964).
The Chemistry of Acyl Halides, S. Patai, Ed., Interscience Publishers, Chap. 12 by D. N. Kevill, pp. 381-399, 407-425, 446-453 (1972).

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