Method for converting natural gas and carbon dioxide to methanol

Chemistry: fischer-tropsch processes; or purification or recover – With preliminary reaction to form hydrogen or a carbon oxide – Gaseous oxygen utilized in the preliminary reaction

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518702, 518704, 518705, 423453, 423458, C07C 2706

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active

057671656

ABSTRACT:
A process for the production of methanol from natural gas containing methane comprising the thermal decomposition of methane and the subsequent reaction of the resulting hydrogen gas with carbon dioxide in a catalyst containing methanol synthesis reactor to produce methanol. Alternative methods include the gasification with carbon dioxide of at least a portion of the carbon produced by the decomposing step, to produce carbon monoxide, which is then reacted with hydrogen gas to produce methanol; or the reforming of a portion of the natural gas feedstock used in the decomposing step with carbon dioxide to produce carbon monoxide and hydrogen gas, which carbon monoxide and hydrogen are then combined with additional hydrogen from the natural gas decomposing step in a methanol synthesis reactor to produce methanol. The methods taught reduce the overall amount of carbon dioxide resulting from the methanol production process.

REFERENCES:
patent: 1803221 (1931-04-01), Tyrer et al.
patent: 5529599 (1996-06-01), Calderon
Kirk-Othmer Encyclopedia of Chemical Technology,vol. 12, p. 965, 1978.
Kirk-Othmer Encyclopedia of Chemical Technology,vol. 15,p. 400, 1978.

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