Method for controlling runaway decomposition in the preparation

Details Method for controlling runaway decomposition in the preparation Method for controlling runaway decomposition in the preparation

1981-01-19

1982-05-11

Lone, Werren B.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568569, 568565, 568570, 568571, C07C17902

Patent

active

043295142

ABSTRACT:
Episodes of accelerated decomposition, or runaway, during the preparation of hydrocarbon hydroperoxides by reaction of hydrocarbons with molecular oxygen at elevated temperature, are brought under control through the addition to the oxidation reaction mixture of a small quantity of base in a substantially instantaneous manner at the onset of the runaway.

REFERENCES:
patent: 2447794 (1948-08-01), Brewer
patent: 2632772 (1953-03-01), Armstrong et al.
patent: 3160668 (1964-12-01), Davue
patent: 4028423 (1977-06-01), Brownstein
patent: 4071561 (1978-01-01), Ciborowski et al.

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