Liquid purification or separation – Processes – Treatment by living organism
Reexamination Certificate
2000-06-15
2001-10-30
Barry, Chester T. (Department: 1724)
Liquid purification or separation
Processes
Treatment by living organism
C210S623000
Reexamination Certificate
active
06309548
ABSTRACT:
FIELD OF THE INVENTION
The invention relates to a method of monitoring and of managing the amount of biomass contained in a station for the biological treatment of municipal or industrial wastewater by activated sludge.
BACKGROUND OF THE INVENTION
In other words, the objective of the invention is to provide a method that can be used to establish an “inventory of the biomass” contained in such a station, this information making it possible, when it is coupled with the amount of biomass extracted from the plant, to quantify the flow of pollution (concentration×flow rate) received by the treatment station. It is then possible to keep the said amount of biomass at an optimum level corresponding to the best possible state of operation of the purification station.
As a consequence of the European directives, the purification techniques currently employed aim to limit discharges, into the natural environment, of untreated wastewater, the stations having to treat all collected water apart from exceptional downpours. The treatment stations have the common characteristics of carrying out a purification by activated sludge, comprising a treatment basin (for example an aeration basin coupled to a clarifier), of being sized on the basis of low COD-BOD loads and of ensuring more of less complete elimination of the nitrogenous pollution.
Furthermore, increased reliability of the stations is required by the European directives and this means that the purification stations have to be strictly monitored and maintained in the best possible state of operation, with a maximum available purifying capacity. In addition, discharge into the natural environment of an effluent of constant quality is an additional constraint, most particularly in cases (which are frequent) in which the pollution load and the flow rate of wastewater to be treated vary very significantly.
It is known that the treatment basin of a purification station contains a homogenous “water/biomass” mixture called mixed liquor. The biomass concentration in the clarifier varies in space and over time. This is due to the settling phenomenon which takes place in the clarifier. It follows that it is impossible to estimate the amount of biomass contained in the clarifier and consequently to estimate the total amount of biomass contained in the plant. Thus, at the present time, no known device for operating and for running plants for water treatment takes into account the management of this “reservoir” of available biomass, although all the conventional actions for controlling the stations are manifested by conservation of the biomass, at least in the case in which the said control results in a stable and balanced operation of the said stations.
The only “evaluation” obtainable by the operator consists in taking a measurement of the concentration of activated sludge, in comparing the result of this measurement with the design-guide value provided by the supplier of the plant and then in adjusting, by successive approximations, the manual extraction of the sludge so as to approach as close as possible this set value. It may therefore be stated that the prior art in this field of the invention with regard to sludge is particularly rudimentary.
However, the problem of monitoring the mass of sludge during clarification is particularly important. Too great a mass of sludge in a clarifier firstly results in anoxic conditions, with an immediate effect of potential denitrification and therefore the appearance of froth on the surface of the said clarifier.
Secondly, the sludge enters under anaerobic conditions, the repercussions of which are often disastrous on the water system and on the treatment of the sludge. This is because, with regard to the water treatment, the development of filamentary microorganisms is favoured, which causes, over the entire station, problems of foaming and of poor floc settling (an increase in the Mohlman index). The risk of sludge entrainment in the clarified water is then increased in the event of a hydraulic surge. The anaerobic conditions are, in addition, completely incompatible with the process of biological dephosphatization and, in this case, the release of phosphorus in the clarifier means that the discharges are immediately off-specification. These events are thus characteristic of a major malfunction with regard to the water system. In parallel, and from a direct economic standpoint, the sludge treatment is not optimized when the floc-settling properties are poor, this being so whatever the treatment system encountered. The times required for operating the equipment of the sludge-treatment system are extended, the solids contents are reduced and, directly, the volumes of sludge extracted are increased for the same mass of dry matter treated.
One characteristic common to biological purification stations (see the figure) is the maintenance of dynamic equilibrium of the system by means of a permanent recirculation of the purifying biomass which is successively transferred from the aeration basin into the clarifier, thereafter to be recirculated from the clarifier into the aeration basin. This recirculation is accomplished using a pump whose capacity determines:
the amount of biomass that can be recirculated; and
indirectly, the mass of biomass which can be maintained in the plant without there being a risk of overaccumulation in the clarifier.
Under equilibrium conditions of the purification treatment, a total mass of biomass present in a given plant allows a maximum permissible flow rate to the plant, above which flow rate a phenomenon of biomass overaccumulation in the clarifier occurs.
This phenomenon has the consequence of keeping the biomass in an unaerated medium for a prolonged period of time. This results in degradation of the biomass due to the lack of oxygen to which it is exposed.
Apart from the damage done to the biomass, an overaccumulation of biological sludge may result in a discharge of biomass mixed with the treated water and therefore in the discharges into the natural environment being off-specification with regard to the content of suspended matter.
The tailoring of the mass of sludge in a plant according to the maximum flow likely to arrive at any instant is therefore essential to the conservation of the natural environment. This tailoring requires a monitoring system capable of evaluating, at a sufficiently high frequency, the total mass of biomass contained in the plant. This is one of the objectives of the present invention.
Moreover, experience shows that the mass load (defined as the flow of pollution to be treated with respect to the amount of biomass present in the plant) is a key parameter for the quality of the water treated. Too high a mass load may result in poor quality of the water treated.
However, since the operator of a purification station has no means of monitoring the flow of pollution to be treated, he has to be able to modify the mass load on his plant and the only adaptable parameter is the variation in the amount of biomass present in the said plant. Knowing the total mass of biomass present in the plant is therefore a key item of information in the running of the biological purification process.
To meet the new European standards on sensitive environments means having to design plants which never exceed their rated load. This constraint has the consequence of frequently operating the plant at hydraulic loads substantially below the rated load. This is especially the case at night. During these periods, the flow entering the plant is small, whereas the flow recirculated from the clarifier into the aeration basin, even if it decreases, must remain at least equal to a value imposed by the recirculating pumps and the hydraulics of the clarifier. This results in transfer of sludge mass from the clarifier into the aeration basin, the mass of the biomass contained in the clarifier becoming negligible compared with the mass contained in the aeration basin.
Analysing the change in the biomass concentration in the aeration basin makes it possible to visualize this phenome
Caulet Philippe
Chatellier Patrice
Barry Chester T.
Connolly Bove Lodge & Hutz
Prince Fred
Suez-Lyonnaise des Eaux
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