Method for controlling a solution process for the...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Effecting a change in a polymerization process in response...

Reexamination Certificate

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C526S059000, C700S269000, C702S030000

Reexamination Certificate

active

07985812

ABSTRACT:
A method for controlling a solution process for the polymerisation of olefins is disclosed. The method is based on an algorithm that calculates predicted operating parameters of the process, including calculation of the extent of reaction (ξ), as a function of the solution density (ρ), and then calculation of the whole composition of the solution. The algorithm resolves a system of equations comprising the equation of state in the PC-SAFT form, the Lewis-Mayo equation for monomer incorporation into a copolymer, and the stoichiometry equation. Predicted parameters are compared to target parameters to detect possible deviations and implement corresponding compensation in the feed.

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Gross et al., “Perturbed-Chain SAFT: An Equation of State Based on a Perturbation Theory for Chain Molecules,”Ind.Eng.Chem.Res.2001, 40, 1244-1260.
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Kouskoumvekaki et al., “Novel Method for Estimating Pure-Component Parameters for Polymers: Application to the PC-SAFT Equation of State,”Ind.Eng.Chem.Res.2004, 43, 2830-2838.
Richards et al., “Measurement and control of polymerization reactors,”Computers&Chemical Engineering2006, 30, 1447-1463.

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