Coating processes – Electrical product produced – Photoelectric
Patent
1983-01-24
1984-11-27
Smith, John D.
Coating processes
Electrical product produced
Photoelectric
427 85, 427 39, 427 87, 4272555, 4272552, 4272557, C23C 1302
Patent
active
044851251
ABSTRACT:
A method and a multiple chamber apparatus for the continuous production of tandem, amorphous, photovoltaic cells on substrate material, whereby, at least six amorphous semiconductor layers are continuously and sequentially deposited on the substrate material under steady state conditions. The substrate material is driven from a supply core, through at least two triads of deposition chambers, to a take-up core. Each amorphous layer of each p-i-n-type cell is produced in one chamber of the triad of deposition chambers. In the first chamber of each triad of chambers, a dopant gas mixture is introduced to deposit a first conductive semiconductor layer atop the substrate. In the second chamber of each triad of chambers, a gas mixture is introduced to deposit an intrinsic layer atop the first layer. And in the third chamber of each triad of chambers, a dopant gas mixture is introduced to deposit a second conductive layer, opposite in conductivity from the first conductive layer, atop the intrinsic layer. The multiple chamber apparatus is constructed to substantially prevent (1) the dopant gases in the first or third chamber of each triad from contaminating the intrinsic gases in the second chamber of each triad of deposition chambers; and (2) the dopant gases in the third chamber of a preceding triad of deposition chambers and the dopant gases in the first chamber of a succeeding triad of deposition chambers from cross-contamination. In the preferred embodiment, the intrinsic material is an amorphous silicon alloy which is doped by boron to form a p-type alloy and doped by phosphorous to form an n-type alloy. The preferred embodiment further contemplates the use of a glow discharge deposition process wherein vacuum pressure conditions, temperature levels, reaction gas mixtures, reaction gas flow rates, cathode power generation levels, substrate speed of travel, and substrate tension are precisely controlled.
REFERENCES:
patent: 2862705 (1958-12-01), Faeber
patent: 3083926 (1963-04-01), Herr
patent: 4015558 (1977-04-01), Small et al.
patent: 4379943 (1983-04-01), Yang et al.
patent: 4410558 (1983-10-01), Izu et al.
patent: 4438723 (1984-03-01), Cannella et al.
Izu Masatsugu
Ovshinsky Herbert C.
Citkowski Ronald W.
Energy Conversion Devices Inc.
Plantz Bernard F.
Siskind Marvin S.
Smith John D.
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