Method for continuous production of a perfluoroalkyl iodide...

Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing

Reexamination Certificate

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C570S175000, C570S171000

Reexamination Certificate

active

06919490

ABSTRACT:
The present invention relates to a process for continuously producing a perfluoroalkyl iodide represented by the general formula Rf(CF2CF2)nI, wherein Rfis a C1-6perfluoroalkyl and n is an integer from 1 to 4, the method comprising continuously supplying a perfluoroalkyl iodide as a telogen represented by the general formula RfI, wherein Rfis as defined above, and tetrafluoroethylene as a taxogen to a tubular reactor packed with a metal catalyst comprising a powdery spherical metal or a sintered metal; and conducting telomerization at a temperature of 60 to 160° C. under a pressure of 0.1 to 5 MPa (gauge pressure).According to the present invention, medium-chain perfluoroalkyl iodides can be continuously and efficiently produced with little generation of impurities, such as hydrogen-containing organic compounds and the like.

REFERENCES:
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patent: 5639923 (1997-06-01), Von Werner
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Q. Chen et al.; “Copper-Induced Telomerization of Tetrafluoro-ethylene with Fluoroalkyl Iodides”;Journal of Fluorine Chemistry; vol. 36; 1987; pp. 483-489./Cited in the International Search Report.

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