Coating processes – With pretreatment of the base – Preapplied reactant or reaction promoter or hardener
Patent
1988-12-23
1993-09-07
Beck, Shrive
Coating processes
With pretreatment of the base
Preapplied reactant or reaction promoter or hardener
427306, C23C 2600
Patent
active
052427137
ABSTRACT:
Certain organic polymeric materials are capable of reversibly accepting or donating electrons from a reducing entity. The redox sites in the polymer accept electrons and, as a result, a change in the properties of the polymer occurs. This change is useful in modifying or etching the polymeric material The material can be modified by incorporation of metallic seeds into the material at a controlled depth. The seeds are incorporated by interaction of cations of the metals with the redox sites in the polymer, which cause the reduction of the cations to form the neutral metallic seeds. Subsequent exposure of the polymeric material containing the seeds to an electroless bath causes further deposition of metal having the desirable characteristic of good adhesion to the polymeric material. Etching of the polymeric material can be carried out as a result of an increase in solubility of the polymer in aprotic solvents when its redox sites have accepted electrons. The increased solubility allows openings to be etched in certain areas of the polymeric material that have been reduced, leaving other areas unchanged.
REFERENCES:
patent: 3073736 (1963-01-01), Lange
patent: 3156608 (1964-11-01), Kamins et al.
patent: 3395057 (1968-07-01), Fick
patent: 3442737 (1969-05-01), Reed et al.
patent: 3567540 (1971-03-01), Tacheci et al.
patent: 3681166 (1972-08-01), Caiola et al.
patent: 3769136 (1973-10-01), Ospelt
patent: 3791848 (1974-02-01), DeAngelo
patent: 3821054 (1974-06-01), Trostyanskaya et al.
patent: 3833436 (1974-09-01), Hillis et al.
patent: 3901755 (1975-08-01), Martin et al.
patent: 3902908 (1975-09-01), Rantell et al.
patent: 3914150 (1975-10-01), Hill, Jr. et al.
patent: 3937857 (1976-02-01), Brummett et al.
patent: 3954570 (1976-05-01), Shirk et al.
patent: 4039371 (1977-08-01), Brunner et al.
patent: 4078096 (1978-03-01), Redmond et al.
patent: 4112139 (1978-09-01), Shirk et al.
patent: 4113550 (1978-09-01), Saiki et al.
patent: 4137117 (1979-01-01), Jones
patent: 4143186 (1979-03-01), Davis
patent: 4261800 (1981-04-01), Beckenbaugh et al.
patent: 4279948 (1981-07-01), Kukanskis et al.
patent: 4305997 (1981-12-01), Feldstein
patent: 4337110 (1982-06-01), Antonoplos et al.
patent: 4353778 (1982-10-01), Fineman et al.
patent: 4369090 (1983-01-01), Wilson et al.
patent: 4399489 (1983-08-01), Ross
patent: 4426253 (1984-01-01), Kreuz et al.
patent: 4431478 (1984-02-01), Yamaoka et al.
patent: 4436583 (1984-03-01), Saiki et al.
patent: 4486273 (1984-12-01), Lutfy et al.
patent: 4508749 (1985-04-01), Brannon et al.
patent: 4512855 (1985-04-01), Mazur
patent: 4517254 (1985-05-01), Grapentin et al.
patent: 4533574 (1985-08-01), Fryd et al.
patent: 4543295 (1985-09-01), St. Clair et al.
patent: 4554182 (1985-11-01), Bupp et al.
patent: 4563371 (1986-01-01), Sirinyan et al.
patent: 4565606 (1986-01-01), Cassat
patent: 4634619 (1987-01-01), Lindsay et al.
patent: 4645734 (1987-02-01), Takada et al.
patent: 4657833 (1987-04-01), Hadley, Jr. et al.
patent: 4668354 (1987-05-01), Levy
patent: 4692360 (1987-09-01), Manring
patent: 4701350 (1987-10-01), Lindsay
patent: 4705720 (1987-11-01), Kundinger et al.
patent: 4710310 (1987-12-01), Shinozaki et al.
patent: 4710403 (1987-12-01), Krause et al.
patent: 4719145 (1988-01-01), Neely
patent: 4752529 (1988-06-01), Manring
patent: 4774157 (1988-09-01), Manring
patent: 4775449 (1988-10-01), Dumas et al.
"Electrochemical Growth of Metal Interlayers in Polyimide Film," Mazur et al., J. Phys. Chem., 1986, 90, pp. 1365-1372.
"Electrochemistry of Aromatic Polyimides," Mazur et al., Journal of Electrochemical Society, Feb. 1987, pp. 346-353.
"Electroless Metallization of Organic Polymers Using the Polymer as a Redox Reagent: Reaction of Polyimide with Zintl Anions," Haushalter et al., Thin Solid Films, 102 (1983), pp. 161-171.
"Electrically Conductive TTF Polymers," Green et al., IBM Technical Disclosure Bulletin, vol. 20, No. 7, p. 2865, Dec. 1977.
The Merck Index, 1983 Edition, p. 473.
European Search Report (partial copy) EP 89 12 1299.
Pickup et al., "Electrodeposition of Metal Particles in Films by a Reducing Redox Polymer," Journal Electrochemical Society: Electrochemical Science and Technology, vol. 130, vol. 11, pp. 2205-2216, Nov. 1980.
Bruce et al., "Synthesis and Characterization of Structured Interphases for Hydrogen Generation. Study of an N,N'-dialkyl-4,4'-bipyridinium redox polymer/Palladium Catalyst System", Journ. Physical Chemistry, 1982, vol. 86, pp. 1552-1568.
Buchwalter Stephen L.
Donson William A.
Glenning John J.
Goldberg Martin J.
Grebe Kurt R.
Beck Shrive
Dang Vi Duong
International Business Machines - Corporation
LandOfFree
Method for conditioning an organic polymeric material does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Method for conditioning an organic polymeric material, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Method for conditioning an organic polymeric material will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-486264