Method for chemically modifying an anionic metal complex

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

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556138, 556146, C07F 1500, C07F 1506

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050618164

ABSTRACT:
A method for chemically modifying an anionic metal complex, by obtaining from an anionic metal complex, insoluble in a non-aqueous solvent and a clathrate compound a clathrate complex thereof with a counter cation of said metal complex, which is soluble in a non-aqueous solvent, and then reacting functional groups of the metal complex, which are not concerned with the coordination of said metal complex, with an organic reagent in the presence of a reaction assistant.

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Bull. Chem. Soc. Japan vol. 48(10), 2991-2993.
Inorganic Chemistry, vol. 27, Jun.-Sep., 1988, American Chemical Society, T. Taura, "Carbon-13 Nuclear Magnetic Resonance Spectra of Potassium (Ethylenediaminetetraacetato) Cobaltate (III) in Organic Solvents", pp. 1841-3436.
Chemical Abstracts, vol. 93, No. 18, Nov. 3, 1980, Columbus, Ohio U.S.A., N. Shinichi, "Three-dimensional Metal Complex Structures with Ambident Propylenediamine Ligands Serving as the Hosts of the Aromatic Guest Molecules. Hofmann-pn and pn-Td Type Clathrates", p. 718, Abstract-No. 93:178 670.
Bull. Chem. Soc. Jpn. 1980, 53(8), 2236-40.

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