Method for catalytic dehydrogenation of hydrocarbons using...

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – Having alkenyl moiety – e.g. – styrene – etc.

Reexamination Certificate

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Reexamination Certificate

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06958427

ABSTRACT:
The present invention relates to a method for catalytic dehydrogenation of alkylaromatic hydrocarbons and more particularly, to a method for catalytic dehydrogenation of alkylaromatic hydrocarbons using carbon dioxide as a soft oxidant in the presence of a heterogeneous catalyst comprising both vanadium and iron, which allows operation at a lower reaction temperature due to improve thermodynamic equilibrium and provides an enhanced conversion of hydrocarbons and energy saving.

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Jong-San Chang, et al., “Effect of Carbon Dioxide in Dehydrogenation of Ethylbenzene to Styrene over Zeolite-Suported Iron Oxide Catalyst,” Bull. Korean Chem. Soc., vol. 19 No. 12, pp 1342-1346 (1998).
Junshi Matsui, Toshiaki Sodesawa and Fumio Nozaki, “Influence of carbon dioxide addition upon decay of activity of a potassium-promoted iron oxide catalyst for dehydrogenation of ethylbenzene,” Applied Catalysis 67, (1991), pp. 1979-188.
Mitsuo-o Sugino, Hiroshi Shimada, Tadotoshi Turuda, Hidetoshi Miura, Naoki Ikenaga, Toshimitsu Suzuki, “Oxidative dehydrogenation of ethylbenzene with carbon monoxide,” Applied Catalysis A: General 121, (1995), pp. 125-137.
Naoki Mimura and Masahiro Saito, “Dehydrogenation of ethylbenzene to styrene over Fe2O3/Al2O3catalysts in the presence of carbon dioxide,” Catalysis Letters 58, (1999), pp. 59-62.
Yoshihiro Sakurai, Takamasa Suzaki, Na-oki Ikenaga, Toshimitsu Suzuki, “Dehydrogenation of ethylbenzene with an activated carbon-supported vanadium catalyst,” Applied Catalysis A: General 192, (2000), pp. 281-288.

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