Method for avoiding the corrosion of the strippers in the urea m

Distillation: processes – separatory – Addition of material to distilland to inhibit or prevent... – For scale inhibiting or corrosion preventing

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203 73, 203 86, 203 89, 203DIG9, 159 472, 159 49, 564 68, 564 73, B01D 334

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047583118

ABSTRACT:
A method for passivating the surface of the strippers of the urea plants, where the temperatures are very high, where the pressures range from 120 to 240 Kg/cm.sup.2 and where the effluent process flow from the synthesis reactor undergoes one or more falling-film evaporations, preferably in countercurrent with a driving gas consisting of NH.sub.3 or CO.sub.2, characterized by the fact that the passivation is carried out by means of a sinergistic combination of oxygen, preferably injected into the bottom of at least one stripper, and of a second passivating agent, preferably injected into the process flow entering the head of at least one stripper, wherein said second passivating agent is injected in the liquid state or as a liquid solution, before or contemporaneously to the start of the evaporation.

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patent: 3488293 (1970-01-01), Hong et al.
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patent: 4311856 (1982-01-01), Inoue et al.
patent: 4321410 (1982-03-01), Ono et al.
General Organic, Belgian Report, Dec. 1963, p. 3.
European Chemical News; Jan. 17, 1969 ("urea supplement"); pp. 17-20.

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