Method for amperometric measurement of the free-chlorine content

Chemistry: electrical and wave energy – Processes and products

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204195R, 23230R, G01N 2746

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active

042785073

ABSTRACT:
A method for measuring the free chlorine content in a solution consists, in first portions of the solution, in successively adding a chemical compound (e.g. a nitrite), which selectively transforms the free chlorine into chloride, then an iodide, in introducing the said first portions in an amperometric cell for measuring the combined chlorine content and, in second portions of the solution, in adding only the iodide and subsequently introducing the second portions into an amperometric cell for measuring the total chlorine content and finally in calculating the difference between the total chlorine and the combined chlorine contents.

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patent: 4129479 (1978-12-01), Morrow
Lambert et al., "Analytical Chemistry", vol. 41, No. 6, May 1969, pp. 838-840.
Zitomer et al., "Analytical Chemistry", vol. 34, No. 13, Dec. 1962, pp. 1738-1740.

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