Method for adjusting methanol to higher alcohol ratios

Details Method for adjusting methanol to higher alcohol ratios Method for adjusting methanol to higher alcohol ratios

1986-02-18

1987-06-23

Mars, Howard T.

Chemistry: fischer-tropsch processes; or purification or recover

Group vib metal containing catalyst utilized for the...

502219, 502220, C07C 2706

Patent

active

046753443

ABSTRACT:
A method for controlling the ratio of methanol to higher alcohols produced in a process for making mixed alcohols by contacting a hydrogen- and carbon monoxide-containing feed with a molybdenum- or tungsten-containing catalyst, said method comprising adjusting a concentration of a sulfur releasing substance in the feed.

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"Catalytic Methanation", G. A. Mills and F. W. Steffgen, Catalysis Reviews, 8(2) 159-210 (1973), pp. 196-198.
"Synthesis of Alcohols by Hydrogenation of Carbon Monoxide", R. B. Anderson et al., Industrial and Engineering Chemistry, 44(10), pp. 2418-2424 (Oct. 1952).
"A Critical Analysis of Recent Advances in CO-H.sub.2 Catalysis", Catalytica Associates, Inc., Santa Clara, CA 95051, Multiclient Study No. 1124 (Jun. 1980).

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