Method for activating strengthened iron catalyst for slurry...

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Organic compound containing

Reexamination Certificate

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C502S336000, C502S327000, C502S326000, C502S302000, C518S715000, C518S700000

Reexamination Certificate

active

07915193

ABSTRACT:
A method of activating an iron Fischer-Tropsch catalyst by introducing an inert gas into a reactor comprising a slurry of the catalyst at a first temperature, increasing the reactor temperature from the first temperature to a second temperature at a first ramp rate, wherein the second temperature is in the range of from about 150° C. to 250° C., introducing synthesis gas having a ratio of H2:CO to the reactor at a space velocity, and increasing the reactor temperature from the second temperature to a third temperature at a second ramp rate, wherein the third temperature is in the range of from about 270° C. to 300° C. The iron Fischer-Tropsch catalyst may be a precipitated unsupported iron catalyst, production of which is also provided.

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patent: 6627666 (2003-09-01), Pedersen
Activity and Selectivity of Precipitated iron Fischer-Tropsch catalysts. By O' Brien et al. (Catalysis AToday 36 (1997) 325-324.
Attrition resistance of spray-dried iron F-T catalysts:effect of activation conditions. by Ron Zhao et al. (Catalysis Today 71 (2002) 319-326.
Activity and Selectivity of Precipitated Iron Fischer-Tropsch Catalysts. (Robert J. O'Brien et al. Catalysis Today (1997) 325-334.
Attrition Resistamce of Spray-Dried Iron F-T Catalysts: Effect of Activation Conditions.(Ron Zhao et al. Catalysis Today (2002) 319-326.
Fischer-Tropsch Synthesis: Activation of Low-Alpha Potassium Promoted Iron Catalysts. (Mingsheng Luo et al. (Fuel processing Technology (2003) 49-65.
International Application No. PCT/US2009/064895 International Search Report dated Jun. 24, 2010, 11 pages.

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