Method and treating solution for phosphating metal surfaces

Metal treatment – Process of modifying or maintaining internal physical... – Processes of coating utilizing a reactive composition which...

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C23C 2212

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052580792

ABSTRACT:
The present invention relates to a phosphating method and solution for forming on a metal surface a phosphate film, which are used for elevating coating finish and rust-preventive property when a product consisting essentially of steel and/or zinc-plated steel combined with an aluminum alloy is coated with cationic electrocoating.
The method and solution comprise that said metal surface is brought, to form a coating film, in contact with an aqueous phosphate solution which satisfies the following conditions with respect to the six kinds of ions contained. A total concentration of a sodium ion and a potassium ion is in a range of 2.0 to 15.0 (g/l). A total concentration of a manganese ion and a nickel ion is in a range of 1.0 to 5.0 (g/l). Concentration of a zinc ion is in a range of (1.6-0.02 T) to (2.5-0.02 T) (g/l). Concentration of a free F.sup.- ion is in a range of 8.0 T.sup.-1 to 20.0 T.sup.-1 (g/l), (here, T is temperature (.degree.C.) of a phosphating solution and in a range of 20 to 60).
Contact of the metal surface with the phosphate solution is carried out with a combined process of dipping treatment subsequently followed by spraying treatment.

REFERENCES:
patent: 1324460 (1973-07-01), Heller
patent: 4717431 (1988-01-01), Kanaster
patent: 4849031 (1989-07-01), Hauffe
patent: 5082511 (1992-01-01), Faring
EP0228151-Jul. 1987.
EP0381190 Aug. 1990.

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