Method and plant for regenerating sulfate electrolyte in steel s

Electrolysis: processes – compositions used therein – and methods – Electrolytic coating – Treating process fluid by means other than agitation or...

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204206, 204238, 204DIG13, 205101, 210712, 210722, 210724, C25D 2118

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056908040

ABSTRACT:
A method and a plant for regenerating zinc sulfate electrolyte in steel strip electrogalvanizing processes by precipitating dissolved iron from electrolyte circulating through a coating cell. A partial quantity of the circulating electrolyte to be regenerated is removed from the coating cell and the dissolved iron is oxidized to Fe.sup.3+ by a redox-controlled addition of oxidizing agents. Subsequently, by raising the pH value to the precipitation limit of Fe.sup.3+ by a controlled addition of a ZnO/water suspension or a ZnCO.sub.3 /water suspension, the dissolved iron is precipitated as sludge. Any excess ZnO or ZnCO.sub.3 is then dissolved by adding fresh electrolyte. The precipitated iron sludge is conducted through a suitable filter such as a filter press, a filter belt, a decanter, etc., and the precipitated iron is filtered out in this manner. Subsequently, the purified partial quantity of the electrolyte is returned to the coating cell.

REFERENCES:
patent: 2080506 (1937-04-01), Rinck et al.
patent: 2200987 (1940-05-01), Hubbell
patent: 3857765 (1974-12-01), Merker et al.
patent: 4416737 (1983-11-01), Austin et al.
patent: 5192418 (1993-03-01), Hughes et al.
Patent Abstracts Of Japan, vol. 13, No. 466 (C-646), 20. Oct. 1989 & JP-A-01 181000 (Kawasaki Steel Corporation), 18. Jul. 1989.

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