Method and device for processing a gas containing hydrogen...

Chemical apparatus and process disinfecting – deodorizing – preser – Chemical reactor – Including external recycle loop

Reexamination Certificate

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C422S198000, C422S211000

Reexamination Certificate

active

06872368

ABSTRACT:
A method for processing a gas containing at least hydrogen sulfide (H2S) and at least sulfur dioxide (SO2), includes the steps of contacting the gas with a liquid solvent containing at least one catalyst in a contacting stage, recovering gaseous effluent substantially containing no hydrogen sulfide and no sulfur dioxide from the contacting stage, and separating liquid sulfur from liquid solvent in a decantation zone downstream of the contacting stage. In order to remove by-products resulting from degradation of the catalyst, a liquid fraction F containing at least solvent, catalyst, sulfur and the solid by-products resulting from degradation of the catalyst is extracted from after the contacting stage. The liquid fraction F is sent to a processing stage distinct from the contacting stage where the liquid fraction F is heated to a temperature at least partially crystallizing the by-products, and the at least partially crystallized by-products separated from the rest of the liquid fraction F containing at least solvent. At least a stream F1comprising solvent, catalyst and sulfur and substantially free of the by-products and a stream F2mostly comprising the by-products are recovered.

REFERENCES:
patent: 4387037 (1983-06-01), Trentham et al.
patent: 5389351 (1995-02-01), Hasebe et al.
patent: 5935547 (1999-08-01), LeComte et al.
patent: 5951961 (1999-09-01), Viltard et al.
patent: 6413488 (2002-07-01), Smith et al.

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