Method and device for improved catalytic activity in the...

Electrolysis: processes – compositions used therein – and methods – Electrolytic material treatment – Gas – vapor – or critical fluid

Reexamination Certificate

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C205S765000, C204S252000, C204S265000, C204S266000, C429S010000

Reexamination Certificate

active

06896792

ABSTRACT:
The activity of catalysts used in promoting the oxidation of certain oxidizable species in fluids can be enhanced via electrochemical methods, e.g., NEMCA. In particular, the activity of catalysts used in the selective oxidation of carbon monoxide can be enhanced. A purification system that exploits this effect is useful in purifying reformate supplied as fuel to a solid polymer electrolyte fuel cell stack. The purification system comprises an electrolytic cell with fluid diffusion electrodes. The activity of catalyst incorporated in the cell anode is enhanced.

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patent: 6245214 (2001-06-01), Rehg et al.
patent: 20020164507 (2002-11-01), Ding et al.
patent: 196 15 562 (1997-10-01), None
patent: 02 311302 (1990-12-01), None
patent: WO 0016880 (2000-03-01), None
English abstract and machine translation of DE 196 15 562, German text from esp@cenet, ep.espacenet.com, Sep. 10, 1997.
English abstract of JP 02 311302, esp@cenet, ep.espacenet.com, Dec. 26, 1990.
Merimadi et al., “Low-Temperature Hydrogen Production Using Electrically Activated Catalysts,”ChemComm:1875-1876, 2000.
Tsiplakides et al., “Nonfarada Electrochemical Modification of The Catalytic Activity of Pt-Black Electrodes Deposited on Nafion 117 Solid Polymer Electrolytes,”Journal of the Electrochemical Society144(6):2072-2078, Jun. 1997.
Vayenas et al., “The Electrochemical Activation of Catalytic Reactions,” in John O'M Bockris et al. (ed.),Modern Aspects of Electrochemistry No. 29, Chapter 2, Plenum Press, New York, 1996, pp. 57-202.

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