Method and catalyst system for producing aromatic carbonates

Organic compounds -- part of the class 532-570 series – Organic compounds – Carbonate esters

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558271, 558272, 558273, 502164, 502302, 502304, 502324, 502325, 502326, 502345, 502353, C07C 6800

Patent

active

061145637

ABSTRACT:
A method and catalyst system for economically producing aromatic carbonates from aromatic hydroxy compounds. In one embodiment, the present invention provides a method of carbonylating aromatic hydroxy compounds by contacting at least one aromatic hydroxy compound with oxygen and carbon monoxide in the presence of a carbonylation catalyst system that includes a catalytic amount of an inorganic co-catalyst containing bismuth. In various alternative embodiments, the carbonylation catalyst system can include an effective amount of a palladium source and an effective amount of a halide composition. Further alternative embodiments can include catalytic amounts of various inorganic co-catalyst combinations.

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