Specialized metallurgical processes – compositions for use therei – Processes – Process control responsive to sensed condition
Reissue Patent
1999-02-08
2002-12-10
Andrews, Melvyn (Department: 1742)
Specialized metallurgical processes, compositions for use therei
Processes
Process control responsive to sensed condition
C250S554000, C266S078000, C266S080000, C266S099000, C356S072000
Reissue Patent
active
RE037922
ABSTRACT:
BACKGROUND OF THE INVENTION
This invention is directed to a method and apparatus for controlling or determining the carbon content of a heat in a BOF vessel, and more particularly, to a method for determining the in-blow carbon content and the First Turn Down Carbon (FTDC), in low carbon steel BOF heats containing 0.06% or less carbon.
Users of flat rolled steel product demand low carbon grade steel because of its good formability properties. For example, in the automotive industry, such low carbon steel permits auto manufacturers to stamp and form complex automobile shapes without encountering steel spring-back after the foraging operations. This makes it necessary for steelmakers to accurately manage and control the carbon content of their BOF heats to produce a product having the proper metallurgical requirements.
In the BOF
steehnaking
steelmaking
process carbon saturated liquid iron is poured into the vessel along with various amounts of steel scrap.
tligh
and high
velocity oxygen is blown into the BOF vessel at the surface of the molten steel bath where it reacts with the carbon to form CO and CO
2
. This reaction removes excess carbon in the steel bath and produces a finished product having the desired carbon content.
There are many BOF process control methods available to preset day steelmakers. These controls range from sophisticated predictive models that are managed through the use of computers in combination with sensor instruments such as gas analyzers, thermocouples, load cells, etc.
In the past, various attempts have been made to control the carbon content in a vessel using flame drop measurements. One such past attempt is shown in U.S. Pat. No. 3,652,262 granted to Denis. This patent discloses using a sensor to detect infrared radiation emitted from a BOF vessel. The signal from the infrared sensor is processed to generate a curve representing a function of radiation intensity against time. In his patent, Denis compared his radiation curve with a decarburization curve generated by using readings taken from a first gas pickup used to measure the concentration of CO
2
and CO in the off-gas of a BOF vessel, and from a second gas pickup used to measure the total gas output. He then compared the two curves and concluded that his time/radiation curve was useful in providing an instantaneous carbon reading during BOF steelmaking operations. However, if the two different graphs are compared, it can be seen that wide variations in predicted carbon levels occur between the off-gas curve and the radiation curve. Therefore, although Denis has provided some improvement in providing an instantaneous reading of carbon content during a heat, his patent shows a wide margin of error in his predicted carbon levels based upon his flame drop readings.
Additionally, in a study found in chapter fifteen entitled “BOF Control”, of an Iron & Steel Society publication “BOF STEELMAKING” dated 1977, J. H. Cox, et al. teach that flame intensity is a function of the carbon in the bath. However, the authors also teach that carbon predictions, based upon flame intensity measurements, are not satisfactory for the more stringent present day needs.
Such beliefs have become widespread throughout the steelmaking industry. They have led steelmakers to use control strategies based on statistical, predictive-adaptive control models, or highly sophisticated control systems based on a continuous or periodic measurement of variables such as carbon, temperature, etc. (J. H. Cox, et al. “BOF STEELMAKING”). One such measurement process is based upon mass/temperature calculations to determine the carbon content of a BOF heat. It is well known that such mass/temperature calculations contain a margin of error, and they often lead to either overblowing or underblowing the BOF heats.
In instances where a heat is overblown various undesirable chemical reactions take place within the vessel. For example, in an overblown heat, the oxygen consumes an excessive amount of carbon and a steel product having an undesirable low carbon level is produced. The excess oxygen also reacts with the molten iron to form iron oxides. This reduces the iron yield of a heat. Overblowing a heat will also overheat the steelmaking vessel, cause premature wear on its protective refractory lining, and reduce the service life of the vessel.
In those instances where a heat is underblown, the heat may have to be reblown to further reduce the carbon level. This increases production time and cost, and causes excess refractory wear. The excess refractory wear is due to the iron oxides that are formed in the slag during the reblow. Iron oxides in the slag make the slag more corrosive to the refractory lining.
Another problem encountered with BOF control systems is dealing with the hostile environment adjacent the hot BOF vessel. The radiant heat emitted from a BOF vessel during the steelmaking process overheats sensitive electronic equipment located near the vessel and causes system failures. Dust and fume released from the vessel also settles on equipment located throughout the steelmaking shop, including the various sensor devices used to control the steelmaking process. The dust and fume causes control equipment sensors to become fouled and dirty, and results in poor readings and inaccurate metallurgical analysis.
SUMMARY OF THE INVENTION
It is therefore an object of this invention to provide a method for determining the carbon content of a BOF heat.
It is still a further object of this invention to accurately control or determine the carbon content of a BOF heat within a margin of error of about 0.004% C.
It is still a further object of this invention to accurately control or determine the carbon content of a BOF heat by measuring a difference in visible light intensity emitted from the BOF vessel in relation to the amount of oxygen blown into the vessel.
It is still a further object of this invention to provide apparatus for controlling and/or determining carbon content of a BOF heat, the apparatus being resistant to high temperatures encountered in the steelmaking process.
And finally, it is still a further object of this invention to provide apparatus, for controlling and/or determining the carbon content of a BOF heat, that includes a self cleaning means to prevent an accumulation of fume or dust on its sensor devices.
We have discovered that the foregoing objects can be attained by measuring a drop in visible light intensity emitted from a BOF vessel with a light sensor housed within a temperature regulated case having a sighting window including air wipe means to shield the light sensor from steelmaking dust and fume. The drop in visible light intensity is measured from a point of maximum light intensity emitted from the BOF vessel in relation to the amount of oxygen blown into the BOF vessel from such point of maximum light intensity, to the end of the oxygen blow. The light intensity and oxygen readings are used to compute continuous, real time in-blow % carbon levels until an aim carbon content is reached for the heat.
REFERENCES:
patent: 2207309 (1940-07-01), Work
patent: 2354400 (1944-07-01), Percy
patent: 2803987 (1957-08-01), Galey
patent: 2807537 (1957-09-01), Murphy
patent: 3591296 (1971-07-01), Kunioka et al.
patent: 3652262 (1972-03-01), Denis
patent: 3669645 (1972-06-01), Oishi et al.
patent: 3719469 (1973-03-01), Roessing
patent: 3720404 (1973-03-01), Carlson et al.
patent: 3741557 (1973-06-01), Harbaugh et al.
patent: 4651976 (1987-03-01), Arima et al.
patent: 2015788 (1970-10-01), None
patent: 1183281 (1970-03-01), None
patent: 43-2835 (1968-02-01), None
patent: 49-113713 (1974-10-01), None
BOF Control, by J. H. Cox, et al.; BOF Steelmaking, pp. 243-288 vol. 4, 1997.
Andrews Melvyn
Bethlehem Steel Corporation
Bethlehem Steel Corporation
Liniak, Berenato, Longacre & White LLC
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