Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy
Patent
1976-04-13
1978-06-20
Williams, Howard S.
Chemistry: electrical and wave energy
Processes and products
Processes of treating materials by wave energy
204163R, 250527, 204DIG11, B01J 110
Patent
active
040960463
ABSTRACT:
Method for separation or enrichment of isotopes bound to anisotopic materials and forming a mixture of isotope compounds by irradiating the mixture of isotope compounds with a first light source to photochemically convert the mixture to a second mixture of isotope compounds, e.g. converting UF.sub.6 to UF.sub.5 and F, irradiating the second mixture in the presence of a reactant with a second light source to selectively excite only one isotope compound of the second mixture, the reactant chemically reacting with the excited compound, e.g. UF.sub.5 .fwdarw.UF.sub.4 + F or UF.sub.5 + R (reactant).fwdarw.UF.sub.4 + RF and separating the reaction products including one of the isotopes of the first mixture.
The separation or enrichment of isotopes may be carried out in apparatus having a highly-reflecting elliptical cylinder with a reaction vessel provided with feed and reactant inlet and reaction products outlet, disposed at one focal line of the elliptical cylinder and a high pressure mercury burner disposed at the second focal line, and with the reaction vessel arranged between resonator mirrors of a dye laser as the second light source.
REFERENCES:
patent: 3443087 (1969-05-01), Robieux et al.
patent: 3719454 (1973-03-01), Shang
patent: 3937956 (1976-02-01), Lyon
IBM Technical Disclosure Bulletin, vol. 17, No. 11 (April 1975) pp. 3501 & 3502.
Kraftwerk Union Aktiengesellschaft
Lerner Herbert L.
Williams Howard S.
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