Chemistry of hydrocarbon compounds – Plural serial diverse syntheses – To produce unsaturate
Reexamination Certificate
2007-01-09
2007-01-09
Price, Elvis O. (Department: 1621)
Chemistry of hydrocarbon compounds
Plural serial diverse syntheses
To produce unsaturate
C585S318000, C585S501000, C568S490000, C568S448000, C568S449000, C568S893000, C568S671000, C568S891000, C568S910000
Reexamination Certificate
active
10430240
ABSTRACT:
A reactant selected from the group consisting of alkanes, alkenes, alkynes, dienes, and aromatics is reacted with a halide selected from the group including chlorine, bromine, and iodine to form a first reaction product. The first reaction product is reacted with a solid oxidizer to form a product selected from the group including olefins, alcohols, ethers, and aldehydes, and spent oxidizer. The spent oxidizer is oxidized to form the original solid oxidizer and the second reactant which are recycled.
REFERENCES:
patent: 3172915 (1965-03-01), Borkowski
patent: 3273964 (1966-09-01), Rosset
patent: 3310380 (1967-03-01), Lester
patent: 3353916 (1967-11-01), Lester
patent: 3894107 (1975-07-01), Butter et al.
patent: 4006169 (1977-02-01), Anderson et al.
patent: 4301253 (1981-11-01), Warren
patent: 4333852 (1982-06-01), Warren
patent: 4373109 (1983-02-01), Olah
patent: 4440871 (1984-04-01), Lok et al.
patent: 4465893 (1984-08-01), Olah
patent: 4496752 (1985-01-01), Gelbein et al.
patent: 4513092 (1985-04-01), Chu et al.
patent: 4523040 (1985-06-01), Olah
patent: 4654449 (1987-03-01), Chang et al.
patent: 4769504 (1988-09-01), Noceti et al.
patent: 4795843 (1989-01-01), Imai et al.
patent: 4982024 (1991-01-01), Lin et al.
patent: 5087786 (1992-02-01), Nubel et al.
patent: 5243098 (1993-09-01), Miller et al.
patent: 5276240 (1994-01-01), Timmons et al.
patent: 5334777 (1994-08-01), Miller et al.
patent: 5486627 (1996-01-01), Quarderer, Jr. et al.
patent: 5998679 (1999-12-01), Miller
patent: 6403840 (2002-06-01), Zhou et al.
patent: 6452058 (2002-09-01), Schweizer et al.
patent: 6462243 (2002-10-01), Zhou et al.
patent: 6465696 (2002-10-01), Zhou et al.
patent: 6465699 (2002-10-01), Grosso
patent: 6472572 (2002-10-01), Zhou et al.
patent: 6486368 (2002-11-01), Zhou et al.
patent: 6525230 (2003-02-01), Grosso
patent: 6713087 (2004-03-01), Tracy et al.
patent: 2002/0198416 (2002-12-01), Zhou et al.
patent: 2003/0069452 (2003-04-01), Sherman et al.
patent: 2003/0078456 (2003-04-01), Yilmaz et al.
patent: 2003/0120121 (2003-06-01), Sherman et al.
patent: 2003/0125583 (2003-07-01), Yilmaz et al.
patent: 2003/0166973 (2003-09-01), Zhou et al.
patent: 2004/0006246 (2004-01-01), Sherman et al.
patent: 0210054 (2004-08-01), None
patent: 2447761 (2002-11-01), None
patent: 2471295 (2003-07-01), None
patent: 1395536 (2004-03-01), None
patent: 1404636 (2004-04-01), None
patent: 1435349 (2004-07-01), None
patent: 1474371 (2004-11-01), None
patent: 2004-529189 (2004-09-01), None
patent: PCT/US99/17980 (1999-08-01), None
patent: WO00/007718 (2000-02-01), None
patent: WO 00/07718 (2000-02-01), None
patent: WO 00/09261 (2000-02-01), None
patent: WO00/09261 (2000-02-01), None
patent: WO 02/094751 (2002-11-01), None
patent: WO 03/000635 (2003-01-01), None
patent: WO 03/022827 (2003-03-01), None
patent: WO 03/062172 (2003-07-01), None
The Catalytic Dehydrohalogenation of Haloethanes on Solid Acids and Bases, Mochida, et al., Bulletin of the Chemical Society of Japan, vol. 44, 3305-3310, 1971.
Nanocrystalline Ultra High Surface Area Magnesium Oxide as a Selective Base Catalyst, Ryan Richards, et al., Scripta Materialia. 44 (2001) 1663-1666.
Nanocrystal Metal Oxide—Chlorine Adducts: Selective Catalysts for Chlorination of Alkanes, Naijian Sun and Kenneth J. Klabunde, J. Am. Chem. Soc., 1999, 121, 5587-5588.
Nanocrystalline MgO as a Dehydrohalogenation Catalyst, Ilya V. Mishakov, et al., Journal of Catalysis 206, 40-48 (2002).
Reactions of VX, GD, and HD with Nanosize CaO: Autocatalytic Dehydrohalogenation of HD, George W. Wagner, et al., J. Phys. Chem. B. 2000, 104, 5118-5123.
Ionic Bromination of Ethane and Other Alkanes (Cycloaklanes) with Bromine Catalyzed by the Polyhalomethane 2AlBr3 Aprotic Organic Superacids under Mild Conditions; Irena S. Akhren, et al.; Tetrahedron Letters, vol. 36, No. 51, pp. 9365-9368, 1995.
Selective bromination of alkanes and arylaklanes with CBr4; Vladimir V. Smirnov, et al., Mendeleev Communications Electronic Version, Issue 5, 2000 (pp. 167-206).
Selective Monohalogenation of Methane over Supported Acid or Platinum Metal Catalysts and Hydrolysis of Methyl Halides over y-Alumina-Supported Metal Oxide/Hydroxide Catalysts. A Feasible Path for the Oxidative Conversion of Methane into Methyl Alcohol/Dimethyl Ether; George B. Olah, et al.; Contribution from the Donald P. and Katherine B. Locker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, Los Angeles, CA; received Apr. 22, 1985.
Electrophilic Methane Conversion; by George A. Olah; Acc. Chem. Res. 1987, 20, 422-428, Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, Los Angeles, CA.
Antimony Pentafluoride/Graphite Catalyzed Oxidative Carbonylation of Methyl Halides with Carbon Monoxide and Copp Oxides (or Copper/Oxygen) to Methyl Acetate; by George A. Olah and Jozef Bukala; J. Org. Chem., 1990, 55, 4293-4297; Donald P. and Katherine B. Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, CA.
Superacid-Catalyzed Carbonylatio of Methane, Methyl Halides, Methyl Alcohol, and Dimethyl Ether to Methyl Acetate a Acetic Acide; by Alessandro Bagno, Jozef Bukala, and George A. Olah; J. Org. Chem. 1990, 55, 4284-4289; Donald P. and Katherine B. Loker Hydrocarbon Research Institute, University of Southern California, University Park, Los Angeles, CA.
The Catalytic Dehydrohalogenation of Haloethanes on Solid Acids and Bases, Mochida, et al., Bulletin of the Chemical Society of Japan, vol. 44, 3305-3310, 1971.
Nanocrystalline Ultra High Surface Area Magnesium Oxide as a Selective Base Catalyst, Ryan Richards, et al., Scripta Materialia, 44, 2001, pp. 1663-1666.
Nanocrystal Metal Oxide- Chlorine Adducts: Selective Catalysts for Chlorination of Alkanes, Naijian Sun and Kenneth J. Klabunde, J. Am. Chem. Soc., 1999, 121, 5587-5588.
Nanocrystalline MgO as a Dehydrohalogenation Catalyst, Ilya V. Mishakov, et al., Journal of Catalysis 206, 40-48, 2002.
Reactions of VX, GD, and HD with Nanosize CaO: Autocatalytic Dehydrohalogenation of HD, George W. Wagner, et al., J. Phys. Chem. B. 2000, 104, 5118-5123.
Changes in Texture and Catalytic Activity of Nanocrystalline MgO during Its Transformation to MgC12 in the Reaction with 1-Chlorobutane, Kenneth J. Klabunde, et al., J. Phys. Chem. B. 2001, 105, 3937-3941.
Ionic Bromination of Ethane and Other Alkanes (Cycloalkanes) with Bromine Catalyzed by the Polyhalomethane 2AlBr3 Aprotic Organic Superacids under Mild Conditions; Irena S. Akhren, et al.; Tetrahedron Letters, vol. 36, No. 51, pp. 9365-9368,1995.
Selective bromination of alkanes and arylalkanes with CBr4; Vladimir V. Smirnov, et al., Mendeleev Communications Electronic Version, Issue 5, 2000 (pp. 167-206).
Selective Monohalogenation of Methane over Supported Acid or Platinum Metal Catalysts and Hydrolysis of Methyl Halides over y-Alumina-Supported Metal Oxide/Hydroxide Catalysts. A Feasible Path for the Oxidative Conversion of Methane into Methyl Alcohol/Dimethyl Ether; George B. Olah, et al.; Contribution from the Donald P. and Katherine B. Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, Los Angeles, CA; received Apr. 22, 1985 (J. Am. Chem. Soc. 1985, 107, 7097-7105).
Electrophilic Methane Conversion; by George A. Olah; Acc. Chem. Res. 1987, 20, 422-428, Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, Los Angeles, California.
Antimony Pentafluoride/Graphite Catalyzed Oxidative Carbonylation of Methyl Halides with Carbon Monoxide and Copper Oxides (or Copper/Oxygen) to Methyl Acetate; by George A. Olah and Jozef Bukala; J. Org. Chem., 1990, 55, No. 14, 4293-4297; Donald P. and Katherine B. Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, University Park, Los Angeles, California.
Superacid-Catalyzed Carbonylation of Methane, Methyl Halides, Methyl Alcohol, and Dimethyl Ether to Methyl Acetate a Acetic Acide; by Ale
Ford Peter
Laverman Leroy E.
Lorkovic Ivan Marc
McFarland Eric W.
Schaefer Dieter J.
Christie Parker & Hale, LLP.
GRT, Inc.
Price Elvis O.
The Regents of the University of California
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