Method and apparatus for removal of h2s from a process gas, incl

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Carbon dioxide or hydrogen sulfide component

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4232421, 423236, 423563, 423567R, 422170, C01B 1716

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active

052157288

ABSTRACT:
A method and apparatus for the hydrothermal treatment of a catalytic polyvalent metal redox absorption solution, after absorption of the H.sub.2 S from an H.sub.2 S containing gas stream, to avoid substantial buildup of thiosulfate salts, cyanide salts, and cyanide complexes in the catalytic polyvalent metal redox solution. The method and apparatus of the present invention is particularly useful for treating gas streams containing both H.sub.2 S and HCN concurrently for destruction of the cyanide salts and cyanide complexes and conversion of H.sub.2 S and by-product salts to elemental sulfur.

REFERENCES:
patent: 3773662 (1973-11-01), Urban
patent: 3941875 (1976-03-01), Tsuruta
patent: 4013430 (1977-03-01), Adachi
patent: 4091074 (1978-05-01), Gorai
patent: 4098886 (1978-07-01), Nicklin
patent: 4387084 (1983-06-01), Brandenburg et al.
patent: 4565678 (1986-01-01), Zielke
patent: 4654148 (1987-03-01), Baker
"Grant and Otackh's Chemical Dictionary", 5th ed. by Roger and Claire Grant, p. 37, 1987.

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