Method and apparatus for measuring dissolved gas concentrations

Chemistry: electrical and wave energy – Processes and products

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204406, 204408, 204412, 204415, G01N 2754

Patent

active

045781540

ABSTRACT:
Two dissolved gas components in sample water, for example, oxygen and hydrogen in core water, are readily quantitatively determined in one and same membrane-type oxygen meter by using a membrane producing an overlapped potential region where a potential region for an oxidation limiting current plateau is overlapped with that for a reduction limiting current plateau between two dissolved gas components, and applying to between a pair of an electrode and a counter-electrode a more positive potential than the equilibrium potential for oxidation-reduction reaction of one of the two dissolved gas components principally, thereby measuring a current generated between the electrodes, and a more negative potential than the equilibrium potential for oxidation-reduction reaction of the other dissolved gas component, when desired, thereby measuring a current generated between the electrodes, and quantitatively determining a concentration of the first dissolved gas component from the latter current quantity and quantitatively determining a concentration of the other dissolved gas component from a difference between the said two current quantities.

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Michael L. Hitchman, "Measurement of Dissolved Oxygen", pp. 71-121, (1978).

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