Method and apparatus for mass selective axial transport...

Radiant energy – Ionic separation or analysis – Cyclically varying ion selecting field means

Reexamination Certificate

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Reexamination Certificate

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07459679

ABSTRACT:
A mass spectrometer system has an elongated rod set having an entrance end, an exit end, a plurality of rods and a central longitudinal axis. The mass spectrometer system is operable to perform the following steps: a) admitting a first plurality of groups of ions into the entrance end of the rod set; b) producing a field between the plurality of rods to confine the first plurality of groups of ions in the rod set; c) selecting a first mass/charge range for a first group of ions in the first plurality of groups of ions; d) providing a first radial excitement field to radially displace the first group of ions within the first mass/charge range from the central longitudinal axis, and concurrently retaining a second group of ions closer to the central longitudinal axis than the first group of ions, the second group of ions being within a second mass/charge range disjoint from the first mass/charge range; and then e) providing a first axial force acting on the first group of ions by providing an axial acceleration field. The first axial force is not provided during step d).

REFERENCES:
patent: 5847386 (1998-12-01), Thomson et al.
patent: 6177668 (2001-01-01), Hager
patent: 6504148 (2003-01-01), Hager
patent: 6630662 (2003-10-01), Loboda
patent: 2005/0253064 (2005-11-01), Loboda et al.
Londry & Hager, “Mass Selective Axial Ejection from a Linear Quadrupole Ion Trap”, J Am Soc Mass Spectrom, 2003, 14, 1130-1147.
Loboda, A., Krutchinsky A., Loboda, O. , McNabb, J., Spicer, V., Ens W., Standing, K. Eur. J. Mass Spectrom. 2000. 6: 531-536.
Written Opinion of the International Searching Authority for application No. PCT/CA2006/001692, p. 1-4.
International Search Report for application No. PCT/CA2006/001692, p. 1-3.

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