Method and apparatus for ion analysis and detection using revers

Liquid purification or separation – Processes – Liquid/liquid solvent or colloidal extraction or diffusing...

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210656, 2101982, 422 70, B01D 1508

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active

044552335

ABSTRACT:
a method of ion analysis and detection of weakly dissociated anions or cations in an eluent by first separating such ions on a chromatographic separation medium by ion exclusion chromatography or mobile phase ion exclusion chromatography. The eluent include an acid or base with a co-ion of the same charge as the ions to be separated, such co-ions being in the hydronium or hydroxide form. In one embodiment the effluent from the separation medium is contacted with one side of an ion-exchange membrane having exchangeable ions of opposite charge to the ionic species. The opposite side of the membrane includes a regenerant with salt-forming suppression ions capable of forming a weakly conducting salt with the co-ions. Then the separated ionic species are detected preferably by a conductivity detector. In another embodiment, the membrane is replaced by a resin bed with ion-exchanging sites of opposite charge to the co-ions. There, co-ions form a suppressed salt with the exchangeable ions.

REFERENCES:
patent: 3598728 (1971-08-01), Bixler et al.
patent: 4265634 (1981-05-01), Pohl
patent: 4314823 (1982-02-01), Rich, Jr. et al.
patent: 4403039 (1983-09-01), Ban et al.

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