Method and apparatus for acetylating cellulose

Organic compounds -- part of the class 532-570 series – Organic compounds – Carbohydrates or derivatives

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536 70, 536 71, 536 73, 536 74, 536 76, 536124, C08B 306, B01J 1900

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058696466

ABSTRACT:
In a production process of a cellulose acetate which comprises (a) a reduced pressure-acetylation step of acetylating a cellulose under a reduced pressure in the presence of sulfuric acid or other acidic catalyst, with distilling off a gaseous phase component of the reaction system out of the system, and (b) a post-acetylation step of allowing the acetylation to further proceed by increasing the pressure as compared with the pressure of the reduced pressure-acetylation step by means of release of the pressure reduction of the reaction system or the like, the shift operation from the reduced pressure-acetylation step to the post-acetylation step is conducted by taking a distilling rate of a distillate in the reduced pressure-acetylation step as an index to control the reaction temperature of the post-acetylation step. The shift operation from the reduced pressure-acetylation step to the post-acetylation step may also be conducted by taking a distilling rate after the distilling rate in the reduced pressure-acetylation step has reached a maximum value.

REFERENCES:
patent: 4590266 (1986-05-01), Yamashita et al.
patent: 5371207 (1994-12-01), Zhuang

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