(Meth) arcylic ester derivatives

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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C07D33902

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active

056706570

ABSTRACT:
A novel compound useful as a precious metal adhesive component is provided which can exhibit high and durable adhesivity with precious metals, such as gold, silver, platinum, and palladium, and alloys thereof. The compound is a (meth)acrylic ester derivative having a disulfide cyclic group which ##STR1## in which R.sub.1 represents a hydrogen atom or a methyl group, and R.sub.2 represents a C1-C14 alkylene group which may have a substituent.

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The Journal of the Japanese Society for Dental Materials and Devices, vol. 5, No. 1, Jan. 1986, pp. 93-105, Katsunori Kojima, "Studies on Adhesion of Functional Monomers with SH Group to Tooth Substrates and Dental Alloys".
The Journal of the Japanese Society for Dental Materials and Devices, vol. 11, Special Issue 20, Sep. 1992, K. Kojima & Y. Kadoma, "Adhesive Property of precious metals treated with disulfide monomer".
The Journal of the Japanese Society for Dental Materials and Devices, vol. 12, Special Issue 21, Apr. 1993, K. Kojima & Y. Kadoma, "The effect of initiator on the adhesion of resin to noble metal surface treated with disulfide monomer".
Sun et al, "Ultrathin self-assembled polymeric films on solid surfaces III. Influence of acrylate dithioalkylside chair length on polymeric monolayer formation on gold", CA 121:135436 (1994).

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