(Meth)acrylate esters, starting alcohols for the preparation...

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

Reexamination Certificate

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C549S295000

Reexamination Certificate

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07041838

ABSTRACT:
A (meth)acrylate represented by the following formula (1):wherein each of R1, R2, R3and R4represents a hydrogen atom, a methyl group or an ethyl group; either one of X1or X2represents a (meth)acryloyloxy group and the other represents a hydrogen atom; both A1and A2represent hydrogen atoms, or A1and A2form —O—, —CH2— or —CH2CH2—, which can be produced by first producing a lactone by reducing an addition product obtained by the Diels-Alder reaction between1,3-diene and maleic anhydride, and then hydrating the lactone to produce an alcohol followed by (meth)acrylation of the alcohol; a polymer produced by (co)polymerizing a monomer composition comprising the (meth)acrylate of the present invention is excellent in transparency, dry etching resistance, and solubility in organic solvents, and so it is preferably used as a resin for a chemically amplified resist composition.

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Atsushi Numata et al.: “Synthesis of pyrolysis products of bisdehydrodihydroenmein. I. Synthesis of 6-hydroxy-7-methylphthalide and 2-(hydroxymethyl)-6,6-dimethyl-5-oxo-1-cyclohexenecarboxylic acid lact one” Yakugaku Zasshi, vol. 88, No. 9, pp. 1151-1162, 1968.

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