Metaphit and related compounds as acylating agents for the (3H)p

Drug – bio-affecting and body treating compositions – Designated organic active ingredient containing – Having -c- – wherein x is chalcogen – bonded directly to...

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558 17, 546229, 514514, C07D21128, A61K 3126, A61K 31445

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active

047628464

ABSTRACT:
A derivative of phencyclidine (1) bearing an isothiocyanate moiety on the meta position of the aromatic ring (3; Metaphit as methanesulfonate and HCl salt) has been synthesized and identified as a rapid and specific site-directed acylating agent of the [.sup.3 H]-phencyclidine binding site in rat brain homogenates. Additional related compounds to Metaphit are Thiophit (oxalate salt), Ethylphit (HCl salt), and Isopropylphit (HCl salt).

REFERENCES:
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patent: 4196185 (1980-04-01), Focella et al.
Quirion et al, Evidence for an Endogenous Peptide Ligand for PCP Recepter, Peptides vol. 5, pp. 967-973 (1984).
Itzhak et al, (I), New Analgesic Drugs Derived from PCP J. Med. Chem 24, pp. 496-499 (1981).
Itzhak et al, II, Receptor Binding and Antinociceptive Prop. of PCP Opiate-Like Derivatives, European J. Pharmacology, 72, pp. 305-311, (1981).
CA 95:24749p, Johnson et al, Synthesis of Amine Derivatives of PCP (1981).

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