Metallocene compound, process for preparing metallocene...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S160000, C526S348200, C526S348600

Reexamination Certificate

active

07449533

ABSTRACT:
The metallocene compound according to the invention and the olefin polymerization catalyst containing the compound are intended to produce a catalyst capable of preparing an isotactic polymer with a high polymerization activity. The metallocene compound contains a substituted cyclopentadienyl group and a (substituted) fluorenyl group and has a structure wherein these groups are bridged by a hydrocarbon group or the like. The process for preparing a metallocene compound according to the invention is intended to selectively prepare a specific metallocene compound so as not to produce an isomer, and in this process an intermediate product is synthesized by a specific method. The process for preparing a polyolefin according to the invention is intended to prepare a polyolefin having excellent impact resistance and transparency, and this process comprises homopolymerizing an α-olefin of 3 to 8 carbon-atoms or copolymerizing an olefin of 3 to 8 carbon atoms and another α-olefin in the presence of an olefin polymerization catalyst containing the above-mentioned metallocene compound.

REFERENCES:
patent: 5723640 (1998-03-01), Fukuoka et al.
patent: 6121182 (2000-09-01), Okumura et al.
patent: 6184318 (2001-02-01), Razavi et al.
patent: 6271164 (2001-08-01), Fritze et al.
patent: 6469188 (2002-10-01), Miller et al.
patent: 6515086 (2003-02-01), Razavi
patent: 0 503 422 (1992-09-01), None
patent: 0577581 (1994-01-01), None
patent: 0 610 847 (1994-08-01), None
patent: 0685495 (1995-12-01), None
patent: 0 747 406 (1996-12-01), None
patent: 0 754 698 (1997-01-01), None
patent: 0 848 022 (1998-06-01), None
patent: 05-059077 (1993-03-01), None
patent: 10 101689 (1998-04-01), None
patent: WO 97/11775 (1997-04-01), None
patent: 97/36937 (1997-10-01), None
patent: WO 97/40075 (1997-10-01), None
patent: 98/02470 (1998-01-01), None
patent: WO98/54230 (1998-12-01), None
patent: 99/02569 (1999-01-01), None
patent: WO99/14219 (1999-03-01), None
patent: WO 00/49056 (2000-08-01), None
Angermund, Klaaus et al.: “The role of intermediate chain migration in propene, polymerization using substituted {iPr(CpFlu)ZrC12/MAO catalysts”; Macromol. Rapid Commun. 21(2), 91-97; Feb. 2000.
Yano, Akihiro et al.: “Ethylene/1-hexene copolymerization with Ph2C (Cp)(Flu)ZrC12 derivatives. Correlation between ligand structure and copolymerization behavior at high temperature”; Macromol. Chem Phys.; 200(6), 1542-1553; 1999.
Ruchatz, Dieter et al.,: “Ethene-Norbornene Copolymerization with Homogeneous Metallocene and Half-sandwich Catalysts: Kinetics and Relationships between Catalyst Structure and Polymer structure. 4. Development of Molecular Weights”; Macromolecules; 31(15); 4684-4686; 1998.
Alt Helmut G., et al: “ansa-Metallocene complexes of type (C13H8-SiR2-C9H6-nR′n)ZrC12 (n=0, 1; R=Me, Ph, alkenyl; R′=alkyl, alkenyl); self-immobilized catalysts for ethylene polymerization”; J. Organomet. Chem; 562(2); 229-253; 1998.
Alt, Helmut G., et al.: “C1-Bridged fluorenylidene-indenylidene complexes of type (C13H8-CR2-C9H6-nR′n)ZrC12 (n=0, 1; R=Me, Ph butenyl; R×=alkyl, alkenyl) as metallocene catalysts for ethylene polymerization”; J. Organomet. Chem., 562(2), 153-181; 1998.
Peifer, Bernd et al.,: “Self-immobilized metallocene catalysts”; J. Organomet. Chem.; 553(1-2); 205-220; 1998.
Stehling, U.M., et al.: “Stereospecific polymerization of functionalized olefins with metallocene catalysts”; Polym. Mater. Sci. Eng.; 76, 244-245; 1997.
Spaleck, Walter et al., “Stereospecific metallocene catalysts: scope and limits of rotational catalyst design”; Macrol. Symp. 89 (Synthetic Structural and Industrial Aspects of Stereospecific Polymerization), 237-247; 1995.
Razavi, Abbas et al.: “Preparation and crystal structures of the complexes (.eta. 5-C5H3Me-CM32-.eta.5-C13H8)MC12 (M=Zr or Hf): mechanistic aspects of the catalytic formation of a syndiotactic-isotactic stereoblock-type Polypropylene”; J. Organomet. Chem.; 497(1-2), 105-111; 1995.
Cavallo, Luigi et al., “A possible model for the stereospecificity in the syndiospecific polymerization of propene with group 4a metallocenes”; Macromolecules, 24(8), 1784-1790; 1991.
Alt et al., J. Organometallic Chemistry 568; 87-112; 1998.
Yano et al., Macromol. Chem. Phys. 200; 1542-1553; 1999.
Office Action issued Sep. 28, 2006 in corresponding Korean Application 10-2001-7007111.

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