Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...
Patent
1995-12-22
1999-10-05
Nazario-Gonzalez, Porfirio
Catalyst, solid sorbent, or support therefor: product or process
Catalyst or precursor therefor
Plural component system comprising a - group i to iv metal...
502104, 502117, 502120, 502132, 526160, 526943, 556 11, 556 53, C08F 4642, C07F 1700, C07F 728
Patent
active
059623594
ABSTRACT:
The present invention relates to a multinuclear metallocene compound of the formula I, ##STR1## where M.sup.1 is a tetravalent metal, L.sup.1 are, independently of one another, identical or different and are each a substituted cyclopentadienyl group, L.sup.2 and L.sup.3 are, independently of one another, identical or different and are each a .pi. ligand, B are, independently of one another, identical or different and are each a divalent bridging unit, X are, independently of one another, identical or different and are each a hydrogen atom, a halogen atom, a C.sub.1 -C.sub.10 -fluorocarbon radical or a hydrocarbon-containing radical having 1-40 carbon atoms, and k is an integer from 0 to 10. The metallocene compound of the present invention is suitable as a catalyst component for preparing olefin polymers.
REFERENCES:
patent: 5324800 (1994-06-01), Welborn, Jr. et al.
patent: 5359102 (1994-10-01), Inoue et al.
patent: 5372980 (1994-12-01), Davis
Aulbach et al., "Metallocene--ma.beta.geschneiderte Werkzeuge zur Herstellung von Polyolefinen", Chemie in unserer Zeit, 28. Jahry. 1994, Nr. 4.
Mohring et al., "Homogeneous Group 4 metallocene Ziegler-Natta catalysts: the influence of cyclopentadienyl-ring substituents", Journal of Organometallic Chemistry, 479 (1994), 1-29.
Diamond et al., "Synthesis of Homo-and Hetero-bimetallic Complexes -C.sub.9 H.sub.6)! Ligand", J. Chem. Soc., Chem. Commun., 1994, 727-728.
Amorose et al., "1--Sila-3-metallacyclobutanes, Precursors for the Generation of Highly Electrophilic Group 4 Metallocene Alkyl Cations. Spectroscopic and Structural Evidence of a Weakly Bound THF Ligand in Organometallics 1991, 10, 2191-2198.
Reddy et al., "Synthesis and Characterization of Binuclear Zirconocene Complexes Linked by a Bridged Bis(cyclopentadienyl) Ligand", Organometallics 1989, 8, 2107-2113.
Reddy et al., "Synthesis and Characterization of Binuclear Zirconocenophane 1989, 8, 547-549.
Kabi-Satpathy et al., "Synthesis and structural characterization of group 4 ansa-metallocene complexes containing a 1-sila-3-metallacyclobutane ring", Journal of Organometallic Chemistry, 364 (1989) 105-117.
Aulbach Michael
Fritze Cornelia
Herrmann Hans-Friedrich
Kuber Frank
Spaleck Walter
Nazario-Gonzalez Porfirio
Targor GmbH
LandOfFree
Metallocene compound and its use as catalyst component does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Metallocene compound and its use as catalyst component, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Metallocene compound and its use as catalyst component will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-1171048