Metallocene catalysts comprising indenyl ligands substituted wit

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...

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502103, 502152, 502154, 502155, 526127, 526160, 526161, 526943, 526172, B01J 3100

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060872926

ABSTRACT:
A highly effective catalyst system for the polymerization of olefins comprises a cocatalyst, preferably an aluminoxane, and a metallocene of the formula I ##STR1## where M.sup.1 =Zr or Hf, R.sup.1 and R.sup.2 =(C.sub.1 -C.sub.3)-alkyl or chlorine, R.sup.3, with the proviso that at least one of the radicals R.sup.3 is not hydrogen, is hydrogen, F, Cl, --OR.sup.7, --NR.sup.7 R.sup.8, --P(O)R.sup.7 R.sup.8, --P(OR.sup.7).sub.2 or SR.sup.7, R.sup.4 is a ##STR2## radical, and m plus n are zero or 1.

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Lee et al, "Organometallics", vol. 11, No. 6, pp. 2155-2122 (1992).
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