Metallocene and process for producing polyolefin using the same

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

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556 9, 556 11, 556 51, 556 52, 556 53, 556 28, 502152, 526127, 526160, C07F 702

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053290313

ABSTRACT:
A metallocene having an asymmetric ligand which is represented by the formula below and its enantiomer: ##STR1## and a process for producing a polyolefin using the same as a catalyst component. The metallocene and its enantiomer are particularly effective in the production of highly stereospecific polyolefins.

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patent: 5132262 (1992-07-01), Rieger et al.
Chemistry Letters, Excellent Stereoregular Isotactic Polymerizatioins of Propylene with C.sub.2 -Symmetric Siliylene-Bridged Metallocene Catalysts, Takaya Mise et al., pp. 1853-1856, 1989.
J. Am. Chem. Soc., vol. 109, pp. 6544-6545, 1987.
J. Am. Chem. Soc., vol. 106, pp. 6355-6364, 1984.
J. Am. Chem. Soc., vol. 110, pp. 6255-6256, 1988.
Polymer Preprints, Japan, vol. 40, p. 265, 1991.
Organometallics, vol. 10, pp. 2061-2068, 1991.

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