Metallocene adduct, its preparation and its application in olefi

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

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556 11, 556 12, 502103, 502117, 526127, 526160, 526173, 526351, 526352, 526943, C07F 1700, C07F 700, C08F 464, B01J 3100

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060574674

ABSTRACT:
This invention relates to an three-constituent adduct of a metallocene.an ether.an metal halide having the general formula of Cp'MQ.sub.2.RXR'.nM'Q.sub.2
, where Cp' is a substituted or an unsubstituted dicyclopentadienyl, M is zirconium or titanium, RXR' is tetrahydrofuran or diethylether, M' is alkali metal or alkali earth metal, n=1 or 2. The adduct can be exposed to air for several hours or stored in nitrogen atmosphere for a long period of time, which is prepared by means of a simple and convenient process without further separation and purification and used directly as a catalyst for polymerization of olefins.

REFERENCES:
patent: 5001205 (1991-03-01), Hoel
patent: 5200537 (1993-04-01), Lee et al.
patent: 5336795 (1994-08-01), Lisowsky

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