Chemistry of inorganic compounds – Carbon or compound thereof – Binary compound
Patent
1993-04-05
1995-11-14
Langel, Wayne
Chemistry of inorganic compounds
Carbon or compound thereof
Binary compound
C01B 3100
Patent
active
054664306
ABSTRACT:
Metallo-carbohedrene compositions, their method of manufacture and use are described. The metal component of the compositions is selected from the group of transition elements and preferably is titanium, zirconium, or vanadium. The compositions of the invention are molecular clusters in the ratio 8:12, metal to carbon respectively. A preferred embodiment is Ti.sub.8 C.sub.12 which has a cage-like structure (suggested 12 pentagonal rings and each of the rings is formed by two titanium and three carbon atoms) where each titanium is bound to three carbons. The compositions of this invention represent a new class of stable molecules (metallo-carbohedrenes) having a variety of applications and are particularly useful as electronic materials and catalysts.
REFERENCES:
patent: 4707384 (1987-11-01), Schachner et al.
patent: 4919974 (1990-04-01), McCue et al.
Pradeep et al. "A Novel F.sub.e C.sub.60 in the Solid State," J. Am. Chem. Soc., 174 (6) Mar. 11, 1992, pp. 2272-2273.
Huang et al. "Externally Bound Metal Ion Complexes of Bulkminsterfullerene, MC.sub.60, in the Gas Phase", J. Am. Chem. Soc. 113(24) Nov. 20, 1991, pp. 9418-9419.
Massalski et al. Binary Alloy Phase Diagrams, vol. 1 American Society for Metals (1986) pp. 593-599, 603-604. (no month).
Wei, et al., Science, vol. 256, pp. 818-820 (1992) no month.
Guo, et al., Science, vol. 255, pp. 1411-1413 (1992) no month.
Guo, et al., Science, vol. 256, pp. 515-516 (1992) no month.
Chen, et al., Journal of Physical Chemistry, vol. 96, No. 23, pp. 9581-9582 (1992).
Chen, et al., Chemical Physics Letters, vol. 198, No. 1, 2, pp. 118-122, (1992). no month.
Pennisi, Science News, vol. 141, pp. 50-251 (1992) no month.
Wei, et al., J. phys. Chem., vol. 96, pp. 4166-4168 (1992) no month.
Guo, et al., J. Chem. Phys., vol. 97, pp. 5243-5245 (1992).
Castleman, Jr. Albert W.
Guo Baochuan
Hendrickson Stuart L.
Langel Wayne
Monahan Thomas J.
The Penn State Research Foundation
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