Metallic derivatives of neopinone ketal

Details Metallic derivatives of neopinone ketal Metallic derivatives of neopinone ketal

1976-03-10

1978-08-29

Rollins, Alton D.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260285, C07F 1500, C07F 314, C07F 500, C07D48902

Patent

active

041103297

ABSTRACT:
Certain mercury, lead, thallium, platinum or palladium derivatives of neopinone dimethyl ketal are provided which are useful as intermediates in the preparation of neopinone alkaloid, for example, 7-acetomercuri neopinone dimethyl ketal. Also provided are processes for preparing such derivatives and neopinone alkaloid.

REFERENCES:
J. Chatt, Chemical Reviews 48, p. 15 (1951).
Kabbe et al., Annalen der Chemie 656, 204-221.
Criegee et al., Angewadte Chemie 70, 173-179 (1958).
Becker et al., Organometalic Reactions vol. 3, pp. 326-327, 343, 354.
Siggia et al., Anal. Chem. 35, 1740-1743 (1963).
Streitwieser, Jr. et al., "Introduction to Organic Chemistry", 1976, p. 377.
March, "Advanced Organic Chemistry; Reactions, Mechanisms and Structure", 1968, pp. 306-307.
Sppenberger et al., Helv. Chim. Acta 51, 381-397 (1968).

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