Metallic copper catalyst for polyfluoroalkylethyl iodide...

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

Reexamination Certificate

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C570S139000, C570S172000

Reexamination Certificate

active

10516940

ABSTRACT:
The present invention provides a metallic copper catalyst for use in an ethylene addition reaction to polyfluoroalkyl iodides, a process for efficiently producing a polyfluoroalkylethyl iodide using such a metal copper catalyst in an ethylene addition reaction to a polyfluoroalkyl iodide, and a process for efficiently producing a polyfluoroalkylethyl iodide from a polyfluoroalkyl iodide using the same metallic copper catalyst in a telomerization reaction and a subsequent ethylene addition reaction.

REFERENCES:
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patent: 4587366 (1986-05-01), von Werner
patent: 4650913 (1987-03-01), Feiring
patent: 5639923 (1997-06-01), Von Werner
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patent: 2002-316956 (2002-10-01), None
patent: 2002-316957 (2002-10-01), None
patent: 2003-183190 (2003-07-01), None
Brace; “Syntheses with perfluoroalkyl radicals from perfluoroalkyl iodides. A rapid survey of synthetic possibilities with emphasis on practical applications. Part one: alkenes, alkynes and allylic compounds”; J. of Fluorine Chemistry 93 (1999) pp. 1-25. (See specification).
Chen et al; “Copper-Induced telomerization of Tetrafluoroethylene with Fluoroalkyl Iodides”; J. Fluorine Chemistry 36 (1987) pp. 483-489. (See Specification).
Von Werner; “Reactions of perfluoroalkyl iodides with CC-multiple bonds induced by transition metal centers”; J. Fluorine Chemistry 28 (1985) pp. 229-233. (See Specification).
International Search Report dated Sep. 2, 2003.

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