Chemistry of inorganic compounds – Zeolite – Organic compound used to form zeolite
Patent
1996-02-06
1998-11-03
Bell, Mark L.
Chemistry of inorganic compounds
Zeolite
Organic compound used to form zeolite
423703, 423713, 423718, 502 62, 502 63, 502 64, 502202, C01B 3904, B01J 2906
Patent
active
058304290
ABSTRACT:
A high silica zeolite (UTD-1) using bis(pentamethyl-cyclopentadienyl)cobalt(III) hydroxide, Cp*.sub.2 CoOH is disclosed. UTD-1 is a large pore molecular sieve having one dimensional channels running in parallel. The synthesis and characterization of silicates incorporating titanium, vanadium, aluminum or boron in the silicate framework is described. Calcined Ti-UTD-1 containing cobalt oxide and the cobalt free molecular sieves are shown to be effective oxidation catalysts. Oxidation of alkanes with hydrogen peroxide and t-butylhydroperoxide (t-BHP) and the room temperature oxidation of cyclohexane to adipic acid are demonstrated.
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Balkus, Jr. Kenneth J.
Gabrielov Alexei G.
Bell Mark L.
Board of Regents , The University of Texas System
Troilo Louis M.
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