Metal phosphine complex

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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Details

26032614A, 26032614T, 2604381, 260557R, 260558R, 260561R, 560250, 562449, 562450, 562567, 562445, 562446, 562444, C07D31710

Patent

active

041208706

ABSTRACT:
Group IB and IIB metal phosphine complexes are disclosed. These complexes are reacted with rhodium complex precursors to form useful enantioselective hydrogenation catalysts. Also disclosed is a method of preparing useful compounds having optical activity such as natural products and compounds useful as flavors and fragrances.

REFERENCES:
patent: 3798241 (1974-03-01), Kagan et al.
Brunie et al., Journ. Organometallic Chem., 114(1976), 225-232.
Consiglio et al., Helv. Chim. Acta, vol. 56, Fasc. 1, Nr. 35-36, 460-463.

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